Static and Dynamic Nanosheets from Selective Assembly of Geometric Macrocycle Isomers
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김용주 | - |
dc.date.accessioned | 2022-04-10T05:40:54Z | - |
dc.date.available | 2022-04-10T05:40:54Z | - |
dc.date.created | 2022-04-08 | - |
dc.date.issued | 2016-10 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/139865 | - |
dc.description.abstract | In contrast to the significant advances that have been made in the construction of two-dimensional (2D) nanostructures, the rational modification from static to dynamic 2D sheets remains a great challenge. Static and dynamic sheets formed from selective self-assembly of geometric macrocycle isomers based on anthracene units are presented. The self-assembly of the cis isomer generates static planar sheets, whereas the trans isomer forms dynamic rolled sheets which are reversibly unrolled upon stimulation by a thermal signal. Furthermore, the mixed solution of the two isomers exhibits self-sorting behavior, generating the coexistence of the two independent self-assembled structures, the planar sheets and the folded scrolls. The self-sorted supramolecular objects with considerable shape and size differences are able to be readily separated, one isomer from the other. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Static and Dynamic Nanosheets from Selective Assembly of Geometric Macrocycle Isomers | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | 김용주 | - |
dc.identifier.doi | 10.1002/anie.201607143 | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.55, no.42, pp.13122 - 13126 | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 55 | - |
dc.citation.number | 42 | - |
dc.citation.startPage | 13122 | - |
dc.citation.endPage | 13126 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | dynamic rolled sheets | - |
dc.subject.keywordAuthor | geometric macrocycle isomers | - |
dc.subject.keywordAuthor | selective assembly | - |
dc.subject.keywordAuthor | self-sorting | - |
dc.subject.keywordAuthor | static planar sheets | - |
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