Functionalization of Organotrifluoroborates via Cu-Catalyzed C-N Coupling Reaction
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김희진 | - |
dc.date.accessioned | 2022-04-11T11:44:41Z | - |
dc.date.available | 2022-04-11T11:44:41Z | - |
dc.date.created | 2022-04-08 | - |
dc.date.issued | 2013-01 | - |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/140015 | - |
dc.description.abstract | Potassium N-heterobiaryltrifluoroborates were successfully prepared via a selective Cu-catalyzed C-N coupling reaction. The BF3K moiety was well tolerated under the reaction conditions involving CuI and dimethylethylenediamine (DMEDA) in the presence of DMSO. The Pd-catalyzed Suzuki-Miyaura cross couplings of potassium N-heterobiaryltrifluoroborates with bromoarenes were studied to prepare the N-heterotriaryl compounds. Moreover, homocoupling, iodination, and hydroxylation of potassium N-heterobiaryltrifluoroborates provided the corresponding products in high yields. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | KOREAN CHEMICAL SOC | - |
dc.title | Functionalization of Organotrifluoroborates via Cu-Catalyzed C-N Coupling Reaction | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | 김희진 | - |
dc.identifier.doi | 10.5012/bkcs.2013.34.1.42 | - |
dc.identifier.bibliographicCitation | BULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.34, no.1, pp.42 - 48 | - |
dc.relation.isPartOf | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.title | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | - |
dc.citation.volume | 34 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 42 | - |
dc.citation.endPage | 48 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.description.journalRegisteredClass | kci | - |
dc.subject.keywordAuthor | Chan-Lam coupling | - |
dc.subject.keywordAuthor | Cu-catalyzed C-N coupling | - |
dc.subject.keywordAuthor | N-Heterobiarene | - |
dc.subject.keywordAuthor | Organotrifluoroborate | - |
dc.subject.keywordAuthor | Potassium N-heterobiaryltrifluoroborates | - |
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