Unveiling the elusive role of tetraethyl orthosilicate hydrolysis in ionic-liquid-templated zeolite synthesis
DC Field | Value | Language |
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dc.contributor.author | Li, X. | - |
dc.contributor.author | Li, T. -h. | - |
dc.contributor.author | Zhou, W. | - |
dc.contributor.author | Li, Y. -p. | - |
dc.contributor.author | Sit, P. H. -L. | - |
dc.contributor.author | Wu, Z. | - |
dc.contributor.author | Curnow, O. J. | - |
dc.contributor.author | Wu, K. C. -W. | - |
dc.contributor.author | Choi, J. | - |
dc.contributor.author | Yip, A. C. K. | - |
dc.date.accessioned | 2022-06-10T23:41:11Z | - |
dc.date.available | 2022-06-10T23:41:11Z | - |
dc.date.created | 2022-06-10 | - |
dc.date.issued | 2022-03 | - |
dc.identifier.issn | 2468-5194 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/141915 | - |
dc.description.abstract | Despite previous reports showing that crystallization kinetics affects zeolite phase selectivity because zeolites are metastable species in their synthesis solution rather than thermodynamic end points, the critical kinetics-controlling parameter is yet to be determined. This work elucidated the effect of tet-raethyl orthosilicate (TEOS) hydrolysis before hydrothermal treatment on the final zeolite phase selec-tivity in the ionic liquid-templated synthesis of 10-membered ring zeolites (MFI-or TON-type zeolites). The results showed that the dissolved silica concentration in the synthesis solution, which is controlled by varying the TEOS hydrolysis temperature and addition rate, induced heterogeneous nuclear growth. Specifically, in 1-butyl-3-methylimidazolium ([BMIM]Br)-directed syntheses, the high and low concen-trations of dissolved silica species led to MFI and TON zeolite formation, respectively. The experimental results are supported by silica polymerization modeling using the Reaction Ensemble Monte Carlo method and theoretical calculations on composite building unit formation. The results are valuable for understanding the nucleation mechanism in zeolite crystallization. (c) 2021 Elsevier Ltd. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCI LTD | - |
dc.subject | STRUCTURE-DIRECTING AGENTS | - |
dc.subject | MOLECULAR-SIEVES | - |
dc.subject | MFI ZEOLITE | - |
dc.subject | SILICALITE-1 CRYSTALLIZATION | - |
dc.subject | GUEST/HOST RELATIONSHIPS | - |
dc.subject | FTIR SPECTROSCOPY | - |
dc.subject | PHASE SELECTIVITY | - |
dc.subject | IN-SITU | - |
dc.subject | NMR | - |
dc.subject | IDENTIFICATION | - |
dc.title | Unveiling the elusive role of tetraethyl orthosilicate hydrolysis in ionic-liquid-templated zeolite synthesis | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Choi, J. | - |
dc.identifier.doi | 10.1016/j.mtchem.2021.100658 | - |
dc.identifier.scopusid | 2-s2.0-85119901307 | - |
dc.identifier.wosid | 000752885400013 | - |
dc.identifier.bibliographicCitation | MATERIALS TODAY CHEMISTRY, v.23 | - |
dc.relation.isPartOf | MATERIALS TODAY CHEMISTRY | - |
dc.citation.title | MATERIALS TODAY CHEMISTRY | - |
dc.citation.volume | 23 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | STRUCTURE-DIRECTING AGENTS | - |
dc.subject.keywordPlus | MOLECULAR-SIEVES | - |
dc.subject.keywordPlus | MFI ZEOLITE | - |
dc.subject.keywordPlus | SILICALITE-1 CRYSTALLIZATION | - |
dc.subject.keywordPlus | GUEST/HOST RELATIONSHIPS | - |
dc.subject.keywordPlus | FTIR SPECTROSCOPY | - |
dc.subject.keywordPlus | PHASE SELECTIVITY | - |
dc.subject.keywordPlus | IN-SITU | - |
dc.subject.keywordPlus | NMR | - |
dc.subject.keywordPlus | IDENTIFICATION | - |
dc.subject.keywordAuthor | Ionic liquids | - |
dc.subject.keywordAuthor | TON | - |
dc.subject.keywordAuthor | MFI | - |
dc.subject.keywordAuthor | TEOS$hydrolysis | - |
dc.subject.keywordAuthor | Zeolites | - |
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