Solvent mediated thermodynamically favorable helical supramolecular self-assembly: recognition behavior towards achiral and chiral analytes
DC Field | Value | Language |
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dc.contributor.author | Kataria, Meenal | - |
dc.contributor.author | Kim, Youngseo | - |
dc.contributor.author | Chau, Hong Diem | - |
dc.contributor.author | Kwon, Na Yeon | - |
dc.contributor.author | Hong, Yongju | - |
dc.contributor.author | Kim, Taekyung | - |
dc.contributor.author | Ko, Jaewan | - |
dc.contributor.author | Son, Myung Kook | - |
dc.contributor.author | Bang, Joona | - |
dc.contributor.author | Park, Sungnam | - |
dc.contributor.author | Kim, Hugh, I | - |
dc.contributor.author | Lee, Kwangyeol | - |
dc.contributor.author | Choi, Dong Hoon | - |
dc.date.accessioned | 2022-08-10T13:40:55Z | - |
dc.date.available | 2022-08-10T13:40:55Z | - |
dc.date.created | 2022-08-10 | - |
dc.date.issued | 2022-07-28 | - |
dc.identifier.issn | 2050-7526 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/142743 | - |
dc.description.abstract | Herein, we successfully developed an entropically favored helical supramolecular self-assembly from a triphenylamine-based derivative 4 in a green solvent in order to mimic the structural transformations that occur during the self-assembly of proteins/peptides which may cause various neurodegenerative diseases. Its structural transformation from helical supramolecular self-assembly to a random call and then achiral nanorods was studied by varying the concentration of achiral stimuli (i.e., Fe2+ ions). The driving force of this transformation is the strong binding affinity of chiral supramolecular assemblies and Fe2+ ions. Furthermore, the "metal-free" helical supramolecular self-assembly exhibited enantioselectivity for differentiating between L- and D-prohne; this was achieved through a chiral stimuli-induced structural modulation methodology. Our evaluation of the effects of achiral/chiral stimuli is also novel. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | AMPLIFICATION | - |
dc.subject | POLYMORPHISM | - |
dc.subject | AGGREGATION | - |
dc.subject | MOLECULES | - |
dc.subject | FIBRILS | - |
dc.subject | BINDING | - |
dc.title | Solvent mediated thermodynamically favorable helical supramolecular self-assembly: recognition behavior towards achiral and chiral analytes | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Bang, Joona | - |
dc.contributor.affiliatedAuthor | Park, Sungnam | - |
dc.contributor.affiliatedAuthor | Kim, Hugh, I | - |
dc.contributor.affiliatedAuthor | Choi, Dong Hoon | - |
dc.identifier.doi | 10.1039/d2tc01113a | - |
dc.identifier.scopusid | 2-s2.0-85134711231 | - |
dc.identifier.wosid | 000823940500001 | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY C, v.10, no.29, pp.10679 - 10685 | - |
dc.relation.isPartOf | JOURNAL OF MATERIALS CHEMISTRY C | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY C | - |
dc.citation.volume | 10 | - |
dc.citation.number | 29 | - |
dc.citation.startPage | 10679 | - |
dc.citation.endPage | 10685 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.subject.keywordPlus | AGGREGATION | - |
dc.subject.keywordPlus | AMPLIFICATION | - |
dc.subject.keywordPlus | BINDING | - |
dc.subject.keywordPlus | FIBRILS | - |
dc.subject.keywordPlus | MOLECULES | - |
dc.subject.keywordPlus | POLYMORPHISM | - |
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