Synthesis and Characterization of Blue Phosphorescent NHC-Ir(III) Complexes with Annulated Heterocyclic 1,2,4-Triazolophenanthridine Derivatives for Highly Efficient PhOLEDs

Abstract

Efficient tris-bidentate Ir(III) phosphorescent dopants were prepared using a series of 1,2,4-triazolo[4,3-f]phenanthridine (tzp) moieties modified with aryl substituents (phenyl, tolyl, and xylenyl) as the main phenylimidazole-based N-heterocyclic carbene (NHC) chelates (C<^>C:). According to the degree of the bulkiness of the aryl substituent and the ligation mode, the five prepared Ir(C-tzp<^>C:) complexes include four homoleptic NHC-Ir(III) complexes, fac-Ir(tzpPh)(3), fac-/mer-Ir(tzpTol)(3), and mer-Ir(tzpXyl)(3), and one heteroleptic NHC-Ir(III) complex, cis-Ir(tzpPh)(2)(tzpPh)', in which the phenyl moiety of one tzpPh ligand is abnormally ligated to the Ir metal center, unlike other tzp ligands. The Ir(III) complexes ligated by carbene ligands (C-tzp<^>C:) exhibited highly efficient emissions in the solid state (Phi(em) = 23.2-54.0%). Electrochemical and theoretical studies revealed that the excited-state properties of these NHC-Ir(III) complexes are variable on the extent of planarity and pi-conjugation of the C-tzp<^>C: chelating ligand. Due to its enhanced rigidity and low excited-state energy, a result of abnormal tzpPh ligand ligation, the heteroleptic cis-Ir(tzpPh)(2)(tzpPh)' exhibited the most efficient emission properties in solution (Phi(em) = 21.4%) and solid (Phi(em) = 54.0%) media. Of the devices fabricated with Ir(C-tzp<^>C:)(3) complexes as emitters, that doped with cisIr(tzpPh)(2)(tzpPh)' exhibited superior electroluminescence efficiencies (external quantum efficiency (EQE) of 16.3%, current efficiency of 27.6 cd A(-1), and power efficiency of 22.1 lm W-1) and CIE coordinates of [0.17,0.26], which are superior to those of other Ir(C-tzp<^>C:)(3) complexes and Ir(dmp)(3) (dmp = 3-(2,6-dimethylphenyl)-7-methylimidazo[1,2-f]phenanthridine). This study provides insight into the molecular-level engineering of Ir(III) dopant materials for improving the emission efficiencies of phosphorescent OLEDs.