One-pot selective production of deoxygenated monomeric, dimeric, and trimeric hydrocarbons from xylose-derived 2-methylfuran using multifunctional tungstate-zirconia-supported Ru, Pd, and Ni catalysts
DC Field | Value | Language |
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dc.contributor.author | Jo, Hyeonmin | - |
dc.contributor.author | Choo, Hyunah | - |
dc.contributor.author | Choi, Jae-Wook | - |
dc.contributor.author | Suh, Dong Jin | - |
dc.contributor.author | Yoo, Chun-Jae | - |
dc.contributor.author | Kim, Chang Soo | - |
dc.contributor.author | Kim, Kwang Ho | - |
dc.contributor.author | Lee, Hyunjoo | - |
dc.contributor.author | Kim, Kyeongsu | - |
dc.contributor.author | Choi, Jungkyu | - |
dc.contributor.author | Ha, Jeong-Myeong | - |
dc.date.accessioned | 2022-08-25T08:40:59Z | - |
dc.date.available | 2022-08-25T08:40:59Z | - |
dc.date.created | 2022-08-25 | - |
dc.date.issued | 2022-08-01 | - |
dc.identifier.issn | 1385-8947 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/143328 | - |
dc.description.abstract | The multifunctionality of tungstate-zirconia-supported metal catalysts was demonstrated in a three-step conversion of 2-methylfuran (2-MF) into deoxygenated C10-15 hydrocarbon fuels in a one-pot reactor, with condensation, hydrogenation, and hydrodeoxygenation performed using single tungstate-zirconia-supported metal catalysts. Manipulation of the reaction conditions, in particular, the reaction temperature and feeding reactant for each reaction step, enabled different catalytic functions of the tungstate-zirconia-supported metals at different reaction stages. Among the metals, Ni favored the production of C-10 hydrocarbons by suppressing further condensation to C-15 compounds, whereas Ru favored the trimerization of 2-MF during the condensation step to produce C-15 hydrocarbons. The superior hydrogenation of 2-MF on Pd reduced the formation of C10-15 compounds. The acidity and hydrogenation activity of the catalysts were investigated to demonstrate the multifunctionality of tungstate-zirconia-supported metals. The catalysts were characterized using H-2 temperature programmed reduction, H-2 temperature programmed desorption, X-ray diffraction, transmission electron microscopy, and nuclear magnetic resonance; the results confirmed the variations in their activity among the different reactions. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | HIGH-QUALITY DIESEL | - |
dc.subject | FUEL PRECURSORS | - |
dc.subject | PYROLYSIS OIL | - |
dc.subject | HYDRODEOXYGENATION | - |
dc.subject | CONDENSATION | - |
dc.subject | BIOMASS | - |
dc.subject | CONVERSION | - |
dc.subject | CELLULOSE | - |
dc.title | One-pot selective production of deoxygenated monomeric, dimeric, and trimeric hydrocarbons from xylose-derived 2-methylfuran using multifunctional tungstate-zirconia-supported Ru, Pd, and Ni catalysts | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Choi, Jungkyu | - |
dc.identifier.doi | 10.1016/j.cej.2022.135581 | - |
dc.identifier.scopusid | 2-s2.0-85127073828 | - |
dc.identifier.wosid | 000821827000001 | - |
dc.identifier.bibliographicCitation | CHEMICAL ENGINEERING JOURNAL, v.441 | - |
dc.relation.isPartOf | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.title | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.volume | 441 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | Y | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | HIGH-QUALITY DIESEL | - |
dc.subject.keywordPlus | FUEL PRECURSORS | - |
dc.subject.keywordPlus | PYROLYSIS OIL | - |
dc.subject.keywordPlus | HYDRODEOXYGENATION | - |
dc.subject.keywordPlus | CONDENSATION | - |
dc.subject.keywordPlus | BIOMASS | - |
dc.subject.keywordPlus | CONVERSION | - |
dc.subject.keywordPlus | CELLULOSE | - |
dc.subject.keywordAuthor | One-pot three-step process | - |
dc.subject.keywordAuthor | Condensation | - |
dc.subject.keywordAuthor | Hydrodeoxygenation | - |
dc.subject.keywordAuthor | Multifunctional catalysts | - |
dc.subject.keywordAuthor | 2-Methylfuran | - |
dc.subject.keywordAuthor | Iso-pentadecane | - |
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