Photocatalytic detoxification of a sulfur mustard simulant under realistic conditions by imidazoline-based porous organic polymer composites
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Hyojin | - |
dc.contributor.author | Shin, Jinwoo | - |
dc.contributor.author | Kang, Dong Won | - |
dc.contributor.author | Kim, Youngseo | - |
dc.contributor.author | Kim, Ji Hyeon | - |
dc.contributor.author | Kang, Minjung | - |
dc.contributor.author | Choe, Jong Hyeak | - |
dc.contributor.author | Park, Sungnam | - |
dc.contributor.author | Kim, Jong Seung | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.date.accessioned | 2022-09-24T14:40:43Z | - |
dc.date.available | 2022-09-24T14:40:43Z | - |
dc.date.created | 2022-09-23 | - |
dc.date.issued | 2022-05-18 | - |
dc.identifier.issn | 2666-3864 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/143895 | - |
dc.description.abstract | Porous materials have recently been explored as highly effective photosensitizers for the photocatalytic detoxification of sulfur mustard. However, most porous material- based photosensitizers are reliant on heavy-metal effects and require non-realistic light sources and O-2-enriched atmosphere to generate reactive oxygen species (ROS). To overcome such health problems and practical limitations, we here report a porous organic polymer (POP) photosensitizer (KUP-3) with a protonated imidazoline core, notably showing the generation of types I and II ROS. Owing to its robust framework, KUP-3 can be incorporated into fabrics or melamine sponges via in situ polymerization. The composite- based photocatalysts (KUP-3@OFb and KUP-3@MSp) exhibit protective and decontamination effects along with the photocatalytic detoxification, even under sunlight irradiation and ambient atmosphere, which is beneficial in real-world applications. This study demonstrates the design and fabrication strategy of a class of POP-based composite materials to enable practical applications for photocatalytic detoxification. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER | - |
dc.subject | SINGLET OXYGEN | - |
dc.subject | SELECTIVE PHOTOOXIDATION | - |
dc.subject | FRAMEWORKS | - |
dc.subject | OXIDATION | - |
dc.subject | EFFICIENT | - |
dc.subject | HD | - |
dc.subject | GD | - |
dc.subject | VX | - |
dc.title | Photocatalytic detoxification of a sulfur mustard simulant under realistic conditions by imidazoline-based porous organic polymer composites | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Park, Sungnam | - |
dc.contributor.affiliatedAuthor | Kim, Jong Seung | - |
dc.contributor.affiliatedAuthor | Hong, Chang Seop | - |
dc.identifier.doi | 10.1016/j.xcrp.2022.100888 | - |
dc.identifier.scopusid | 2-s2.0-85130200965 | - |
dc.identifier.wosid | 000840855100003 | - |
dc.identifier.bibliographicCitation | CELL REPORTS PHYSICAL SCIENCE, v.3, no.5 | - |
dc.relation.isPartOf | CELL REPORTS PHYSICAL SCIENCE | - |
dc.citation.title | CELL REPORTS PHYSICAL SCIENCE | - |
dc.citation.volume | 3 | - |
dc.citation.number | 5 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | Y | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Multidisciplinary | - |
dc.subject.keywordPlus | SINGLET OXYGEN | - |
dc.subject.keywordPlus | SELECTIVE PHOTOOXIDATION | - |
dc.subject.keywordPlus | FRAMEWORKS | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | HD | - |
dc.subject.keywordPlus | GD | - |
dc.subject.keywordPlus | VX | - |
dc.subject.keywordAuthor | ambient condition | - |
dc.subject.keywordAuthor | chemical warfare agent | - |
dc.subject.keywordAuthor | composite | - |
dc.subject.keywordAuthor | heavy-metal free | - |
dc.subject.keywordAuthor | photocatalyst | - |
dc.subject.keywordAuthor | photocatalytic oxidation | - |
dc.subject.keywordAuthor | photosensitizer | - |
dc.subject.keywordAuthor | porous organic polymer | - |
dc.subject.keywordAuthor | reactive oxygen species | - |
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