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Mild and efficient desulfurization of thiiranes with MoCl5/Zn system
- Authors
- Yoo, Byung Woo; Lee, Yeong Jin; Shin, Jeong Won
- Issue Date
- 3월-2022
- Publisher
- TAYLOR & FRANCIS LTD
- Keywords
- Desulfurization; thiirane; alkene; molybdenum(V) chloride; zinc
- Citation
- JOURNAL OF SULFUR CHEMISTRY, v.43, no.2, pp.124 - 131
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF SULFUR CHEMISTRY
- Volume
- 43
- Number
- 2
- Start Page
- 124
- End Page
- 131
- ISSN
- 1741-5993
- Abstract
- Desulfurization of a variety of thiiranes to alkenes occurs chemoselectively in high yields upon treatment with MoCl5/Zn system under mild conditions. The new methodology demonstrates high functional group tolerance toward chloro, bromo, fluoro, methoxy, ester, ether and keto groups.
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