Cationic-potential tuned biphasic layered cathodes for stable desodiation/sodiation
- Authors
- Gao, Xu; Liu, Huanqing; Chen, Hongyi; Mei, Yu; Wang, Baowei; Fang, Liang; Chen, Mingzhe; Chen, Jun; Gao, Jinqiang; Ni, Lianshan; Yang, Li; Tian, Ye; Deng, Wentao; Momen, Roya; Wei, Weifeng; Chen, Libao; Zou, Guoqiang; Hou, Hongshuai; Kang, Yong-Mook; Ji, Xiaobo
- Issue Date
- 15-8월-2022
- Publisher
- ELSEVIER
- Keywords
- Biphasic structure; Cathode materials; Cationic potential; Layered oxides; Sodium -ion batteries
- Citation
- SCIENCE BULLETIN, v.67, no.15, pp.1589 - 1602
- Indexed
- SCIE
SCOPUS
- Journal Title
- SCIENCE BULLETIN
- Volume
- 67
- Number
- 15
- Start Page
- 1589
- End Page
- 1602
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/144102
- DOI
- 10.1016/j.scib.2022.06.024
- ISSN
- 2095-9273
- Abstract
- Sodium layered oxides generally suffer from deep-desodiation instability in P2 structure and sluggish kinetics in O3 structure. It will be great to design P2/O3 biphasic materials that bring the complementary merits of both structures. However, such exploration is hindered by the ambiguous mechanism of material formation. Herein, supported by theoretical simulations and various spectroscopies, we prove that P2/O3 biphasic structures essentially originate from the internal heterogeneity of cationic potential, which can be realized by constraining the temperature-driven ion diffusion during solid-state reactions. Consequently, P2/O3 biphasic Na0.7Ni0.2Cu0.1Fe0.2Mn0.5O2-d with well-designed quaternary composition is successfully obtained, exhibiting much-improved rate capabilities (62 mAh g-1 at 2.4 A g-1) and cycling stabilities (84% capacity retention after 500 cycles) than its single-phase analogues. Furthermore, synchrotron-based diffraction and X-ray absorption spectroscopy are employed to unravel the underlying sodium-storage mechanism of the P2/O3 biphasic structure. This work presents new insights toward the rational design of advanced layered cathodes for sodium-ion batteries.(c) 2022 Science China Press. Published by Elsevier B.V. and Science China Press. All rights reserved.
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