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A Stereodivergent Strategy for Total Syntheses of Antirhine Alkaloids
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Park, Eunjoon | - |
| dc.contributor.author | Bae, Cheolwoo | - |
| dc.contributor.author | Cho, Cheon-Gyu | - |
| dc.contributor.author | Cheon, Cheol-Hong | - |
| dc.date.accessioned | 2021-08-30T02:14:59Z | - |
| dc.date.available | 2021-08-30T02:14:59Z | - |
| dc.date.created | 2021-06-19 | - |
| dc.date.issued | 2021-03-19 | - |
| dc.identifier.issn | 0022-3263 | - |
| dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/49348 | - |
| dc.description.abstract | Total syntheses of the antirhine alkaloids are described. The cyanide-catalyzed imino-Stetter reaction of the aldimine derived from ethyl 2-aminocinnamate and 4-bromopyridine-2-carboxaldehyde provided a 2-pyridinyl substituted indole-3-acetate, which was further converted into the corresponding indoloquinolizidinium intermediate through C-ring formation. Subsequent trans-selective installation of the homoallylic alcohol side-chain at C-15 in the resulting indoloquinolizidinium allowed the total syntheses of antirhine and its known epimer. | - |
| dc.language | English | - |
| dc.language.iso | en | - |
| dc.publisher | AMER CHEMICAL SOC | - |
| dc.title | A Stereodivergent Strategy for Total Syntheses of Antirhine Alkaloids | - |
| dc.type | Article | - |
| dc.contributor.affiliatedAuthor | Cheon, Cheol-Hong | - |
| dc.identifier.doi | 10.1021/acs.joc.0c02936 | - |
| dc.identifier.scopusid | 2-s2.0-85103319078 | - |
| dc.identifier.wosid | 000631442900013 | - |
| dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.86, no.6, pp.4497 - 4511 | - |
| dc.relation.isPartOf | JOURNAL OF ORGANIC CHEMISTRY | - |
| dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
| dc.citation.volume | 86 | - |
| dc.citation.number | 6 | - |
| dc.citation.startPage | 4497 | - |
| dc.citation.endPage | 4511 | - |
| dc.type.rims | ART | - |
| dc.type.docType | Article | - |
| dc.description.journalClass | 1 | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
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