High-capacity sulfur copolymer cathode with metallic fibril-based current collector and conductive capping layer
DC Field | Value | Language |
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dc.contributor.author | Shin, Dongyeeb | - |
dc.contributor.author | Song, Yongkwon | - |
dc.contributor.author | Nam, Donghyeon | - |
dc.contributor.author | Moon, Jun Hyuk | - |
dc.contributor.author | Lee, Seung Woo | - |
dc.contributor.author | Cho, Jinhan | - |
dc.date.accessioned | 2021-08-30T03:58:33Z | - |
dc.date.available | 2021-08-30T03:58:33Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2021-01-28 | - |
dc.identifier.issn | 2050-7488 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/50055 | - |
dc.description.abstract | Highly conductive and porous current collectors that can provide favorable interfacial interaction with sulfur components play a critical role in the performance of lithium-sulfur (Li-S) batteries. Although three-dimensional (3D) porous textiles have emerged as promising current collector materials, most reported approaches have reached a limit in producing textiles with metal-like conductivity and do not effectively utilize the large surface area of textiles. Here, we introduce a Li-S copolymer cathode with high areal/specific capacity and good rate capability using a metallic cotton textile (CT)-based current collector that exhibits strong interfacial interaction with sulfur. To fabricate the metallic current collector, CT was first carbonized and subsequently electroplated with nickel (Ni). When a sulfur copolymer-based hybrid slurry and layer-by-layer-assembled conductive capping layer were deposited onto the Ni-electroplated CT, the resulting Li-S copolymer cathode displayed significantly enhanced areal capacity, specific capacity, and rate capability. These improvements were realized due to the full utilization of the large conductive surface area of Ni-electroplated CT as well as the effective chemical confinement of soluble lithium polysulfides by a conductive capping layer. The Li-S copolymer cathode prepared in this study outperforms previously reported sulfur copolymer-based cathodes and provides a basis for the development and design of future high-performance electrodes. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | High-capacity sulfur copolymer cathode with metallic fibril-based current collector and conductive capping layer | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Cho, Jinhan | - |
dc.identifier.doi | 10.1039/d0ta09516h | - |
dc.identifier.scopusid | 2-s2.0-85100424817 | - |
dc.identifier.wosid | 000614172600035 | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY A, v.9, no.4, pp.2334 - 2344 | - |
dc.relation.isPartOf | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.citation.volume | 9 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 2334 | - |
dc.citation.endPage | 2344 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Energy & Fuels | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Energy & Fuels | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
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