Metal-organic framework-derived MoSx composites as efficient electrocatalysts for hydrogen evolution reaction
DC Field | Value | Language |
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dc.contributor.author | Do, Ha Huu | - |
dc.contributor.author | Quyet Van Le | - |
dc.contributor.author | Tekalgne, Mahider Asmare | - |
dc.contributor.author | Anh Vy Tran | - |
dc.contributor.author | Lee, Tae Hyung | - |
dc.contributor.author | Hong, Sung Hyun | - |
dc.contributor.author | Han, Sang Mok | - |
dc.contributor.author | Ahn, Sang Hyun | - |
dc.contributor.author | Kim, Young Ju | - |
dc.contributor.author | Jang, Ho Won | - |
dc.contributor.author | Kim, Soo Young | - |
dc.date.accessioned | 2021-08-30T03:59:41Z | - |
dc.date.available | 2021-08-30T03:59:41Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2021-01-25 | - |
dc.identifier.issn | 0925-8388 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/50066 | - |
dc.description.abstract | Metal-organic frameworks (MOFs) have emerged as a class of crystalline porous material for energy-related applications. Many MOF-based materials are efficient catalysts for hydrogen evolution reactions (HERs). Herein, we illustrate a strategy to modify Co-based MOFs into amorphous molybdenum sulfide (MoSx) via a facial solvothermal method. The modification gives rise to CoMoS phases that reduce hydrogen adsorption energy of catalysts. As a result, MoSx substantially improves the catalytic activity of Co-based MOF for HERs. An optimal sample with 40% MoSx delivered the best HER performance with a low onset potential of -147 mV and a Tafel slope of similar to 68 mV decade(-1). Furthermore, the composite catalyst was stable for up to 1000 cycles without any changes in performance. These results suggest that the MoSx/Co-MOF-74 composite is a viable candidate for replacing noble metals as a high-performance catalyst for HER in the future. (C) 2020 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | CATALYTIC-ACTIVITY | - |
dc.subject | DRUG-DELIVERY | - |
dc.subject | GRAPHENE | - |
dc.subject | SURFACE | - |
dc.subject | MECHANISM | - |
dc.subject | OXIDATION | - |
dc.subject | CAPACITY | - |
dc.subject | SITES | - |
dc.subject | FILMS | - |
dc.subject | 2D | - |
dc.title | Metal-organic framework-derived MoSx composites as efficient electrocatalysts for hydrogen evolution reaction | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Soo Young | - |
dc.identifier.doi | 10.1016/j.jallcom.2020.156952 | - |
dc.identifier.scopusid | 2-s2.0-85090213847 | - |
dc.identifier.wosid | 000579878700035 | - |
dc.identifier.bibliographicCitation | JOURNAL OF ALLOYS AND COMPOUNDS, v.852 | - |
dc.relation.isPartOf | JOURNAL OF ALLOYS AND COMPOUNDS | - |
dc.citation.title | JOURNAL OF ALLOYS AND COMPOUNDS | - |
dc.citation.volume | 852 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Metallurgy & Metallurgical Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Metallurgy & Metallurgical Engineering | - |
dc.subject.keywordPlus | CATALYTIC-ACTIVITY | - |
dc.subject.keywordPlus | DRUG-DELIVERY | - |
dc.subject.keywordPlus | GRAPHENE | - |
dc.subject.keywordPlus | SURFACE | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | CAPACITY | - |
dc.subject.keywordPlus | SITES | - |
dc.subject.keywordPlus | FILMS | - |
dc.subject.keywordPlus | 2D | - |
dc.subject.keywordAuthor | Metal-organic framework | - |
dc.subject.keywordAuthor | Hydrogen evolution reaction | - |
dc.subject.keywordAuthor | Electrocatalyst | - |
dc.subject.keywordAuthor | MoSx | - |
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