Dimensional selective syntheses of metal-organic frameworks using mixed organic ligands
DC Field | Value | Language |
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dc.contributor.author | Lee, Giseong | - |
dc.contributor.author | Yoon, Jung Heum | - |
dc.contributor.author | Kwon, Kangin | - |
dc.contributor.author | Han, Hogyu | - |
dc.contributor.author | Song, Jeong Hwa | - |
dc.contributor.author | Lim, Kwang Soo | - |
dc.contributor.author | Lee, Woo Ram | - |
dc.date.accessioned | 2021-08-30T06:09:16Z | - |
dc.date.available | 2021-08-30T06:09:16Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2020-12-01 | - |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/50865 | - |
dc.description.abstract | Three metal-organic frameworks (MOFs), Zn(BTX)(m)(L)(n) 1-3 (BTX = 1,4-bis((1H-1,2,4-triazol-1-yl)methyl) benzene; H2L = H(2)IPA (isophthalic acid), H2BDC (terephthalic acid), and H2NDC (naphthalene-2,6-dicarboxylic acid) for 1-3, respectively), were synthesized, and their structures and properties were analyzed. They were prepared by solvothermal reaction of the corresponding mixed ligands with the Zn2+ ion. Single-crystal XRD (SXRD) analysis revealed that 1 and 2 exhibit a 2D layer-stacked structure, whereas 3 shows a 3-fold interpenetrated 3D structure. TGA showed that the structure is thermally stable up to about 350, 317, and 400 degrees C for 1-3, respectively. PXRD showed their structural changes during drying processes. Unlike 1 and 2, only 3 exhibited a sorption isotherm for both N-2 at 77 K and CO2 at 195 K, which showed typical type III and I behaviors, respectively. Thus, the properties of 1-3 are in close connection with dimensionality, which differs depending on their organic ligands. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | CARBON-DIOXIDE CAPTURE | - |
dc.subject | HYDROGEN STORAGE | - |
dc.subject | STRUCTURAL DIVERSITY | - |
dc.subject | CRYSTAL-STRUCTURES | - |
dc.subject | FLUE-GAS | - |
dc.subject | ADSORPTION | - |
dc.subject | SERIES | - |
dc.subject | CO2 | - |
dc.subject | CONSTRUCTION | - |
dc.subject | SEPARATION | - |
dc.title | Dimensional selective syntheses of metal-organic frameworks using mixed organic ligands | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Han, Hogyu | - |
dc.identifier.doi | 10.1016/j.ica.2020.119739 | - |
dc.identifier.scopusid | 2-s2.0-85090557161 | - |
dc.identifier.wosid | 000579557300001 | - |
dc.identifier.bibliographicCitation | INORGANICA CHIMICA ACTA, v.513 | - |
dc.relation.isPartOf | INORGANICA CHIMICA ACTA | - |
dc.citation.title | INORGANICA CHIMICA ACTA | - |
dc.citation.volume | 513 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.subject.keywordPlus | CARBON-DIOXIDE CAPTURE | - |
dc.subject.keywordPlus | HYDROGEN STORAGE | - |
dc.subject.keywordPlus | STRUCTURAL DIVERSITY | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURES | - |
dc.subject.keywordPlus | FLUE-GAS | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | SERIES | - |
dc.subject.keywordPlus | CO2 | - |
dc.subject.keywordPlus | CONSTRUCTION | - |
dc.subject.keywordPlus | SEPARATION | - |
dc.subject.keywordAuthor | Metal-organic frameworks | - |
dc.subject.keywordAuthor | Dimensionality | - |
dc.subject.keywordAuthor | 2D layer structure | - |
dc.subject.keywordAuthor | Interpenetrated structure | - |
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