Enhanced catalytic performance and changed reaction chemistry for electrochemical glycerol oxidation by atomic-layer-deposited Pt-nanoparticle catalysts
DC Field | Value | Language |
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dc.contributor.author | Han, Jisu | - |
dc.contributor.author | Kim, Youngmin | - |
dc.contributor.author | Jackson, David H. K. | - |
dc.contributor.author | Chang, Hyunju | - |
dc.contributor.author | Kim, Hyun Woo | - |
dc.contributor.author | Lee, Jechan | - |
dc.contributor.author | Kim, Jeong-Rang | - |
dc.contributor.author | Noh, Yuseong | - |
dc.contributor.author | Kim, Won Bae | - |
dc.contributor.author | Lee, Kwan-Young | - |
dc.contributor.author | Kim, Hyung Ju | - |
dc.date.accessioned | 2021-08-30T14:03:50Z | - |
dc.date.available | 2021-08-30T14:03:50Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2020-09-15 | - |
dc.identifier.issn | 0926-3373 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/53150 | - |
dc.description.abstract | Atomically controlled thin TiO2 layers were coated onto a carbon-supported Pt nanoparticle (Pt/C) surface using an atomic layer deposition (ALD) technique. Then, the resulting TiO2 coated Pt/C (ALD(TiO2)-Pt/C) was heat-treated at 150 degrees C under N-2 atmosphere. The heat-treated ALD(TiO2)-Pt/C (ALD(TiO2)-Pt/C(150 H T)) catalyst demonstrated improved electrocatalytic glycerol oxidation reaction (GOR) activity with a turnover frequency (TOF) 3-times higher than for uncoated Pt/C catalyst. Interestingly, the ALD(TiO2)-Pt/C(150 H T) catalyst maintained its catalytic GOR performance after a cyclic voltammetry (CV) stability test of 1200 cycles, preventing Pt sintering due to strong Pt-TiO2 interaction. The reaction chemistry for GOR on the ALD(TiO2)-Pt/C(150 H T) catalyst also changed due to the newly created Pt-TiO2 interfaces, producing more oxidized chemicals such as glyceric acid and glycolic acid. The enhanced GOR performance is related to the formation of new Pt-O-Ti bonds and to change in the physicochemical properties of the Pt by interaction between the Pt nanoparticles and ALD-coated TiO2. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER | - |
dc.subject | OXYGEN REDUCTION REACTION | - |
dc.subject | REDUCED GRAPHENE OXIDE | - |
dc.subject | SELECTIVE OXIDATION | - |
dc.subject | ELECTROCATALYTIC OXIDATION | - |
dc.subject | ETHYLENE-GLYCOL | - |
dc.subject | FUEL-CELL | - |
dc.subject | PLATINUM | - |
dc.subject | ELECTROOXIDATION | - |
dc.subject | TIO2 | - |
dc.subject | PD | - |
dc.title | Enhanced catalytic performance and changed reaction chemistry for electrochemical glycerol oxidation by atomic-layer-deposited Pt-nanoparticle catalysts | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lee, Kwan-Young | - |
dc.identifier.doi | 10.1016/j.apcatb.2020.119037 | - |
dc.identifier.scopusid | 2-s2.0-85084092629 | - |
dc.identifier.wosid | 000536933200013 | - |
dc.identifier.bibliographicCitation | APPLIED CATALYSIS B-ENVIRONMENTAL, v.273 | - |
dc.relation.isPartOf | APPLIED CATALYSIS B-ENVIRONMENTAL | - |
dc.citation.title | APPLIED CATALYSIS B-ENVIRONMENTAL | - |
dc.citation.volume | 273 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | OXYGEN REDUCTION REACTION | - |
dc.subject.keywordPlus | REDUCED GRAPHENE OXIDE | - |
dc.subject.keywordPlus | SELECTIVE OXIDATION | - |
dc.subject.keywordPlus | ELECTROCATALYTIC OXIDATION | - |
dc.subject.keywordPlus | ETHYLENE-GLYCOL | - |
dc.subject.keywordPlus | FUEL-CELL | - |
dc.subject.keywordPlus | PLATINUM | - |
dc.subject.keywordPlus | ELECTROOXIDATION | - |
dc.subject.keywordPlus | TIO2 | - |
dc.subject.keywordPlus | PD | - |
dc.subject.keywordAuthor | Platinum nanoparticle | - |
dc.subject.keywordAuthor | Titanium dioxide | - |
dc.subject.keywordAuthor | Atomic layer deposition | - |
dc.subject.keywordAuthor | Electrocatalytic oxidations | - |
dc.subject.keywordAuthor | Glycerol | - |
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