Multiply Charged Conjugated Polyelectrolytes as a Multifunctional Interlayer for Efficient and Scalable Perovskite Solar Cells
DC Field | Value | Language |
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dc.contributor.author | Jung, Eui Dae | - |
dc.contributor.author | Harit, Amit Kumar | - |
dc.contributor.author | Kim, Do Hui | - |
dc.contributor.author | Jang, Chung Hyeon | - |
dc.contributor.author | Park, Jong Hyun | - |
dc.contributor.author | Cho, Shinuk | - |
dc.contributor.author | Song, Myoung Hoon | - |
dc.contributor.author | Woo, Han Young | - |
dc.date.accessioned | 2021-08-30T20:30:25Z | - |
dc.date.available | 2021-08-30T20:30:25Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2020-07 | - |
dc.identifier.issn | 0935-9648 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/54917 | - |
dc.description.abstract | A series of anionic conjugated polyelectrolytes (CPEs) is synthesized based on poly(fluorene-co-phenylene) by varying the side-chain ionic density from two to six per repeat units (MPS2-TMA, MPS4-TMA, and MPS6-TMA). The effect of MPS2, 4, 6-TMA as interlayers on top of a hole-extraction layer of poly(bis(4-phenyl)-2,4,6-trimethylphenylamine (PTAA) is investigated in inverted perovskite solar cells (PeSCs). Owing to the improved wettability of perovskites on hydrophobic PTAA with the CPEs, the PeSCs with CPE interlayers demonstrate a significantly enhanced device performance, with negligible device-to-device dependence relative to the reference PeSC without CPEs. By increasing the ionic density in the MPS-TMA interlayers, the wetting, interfacial defect passivation, and crystal growth of the perovskites are significantly improved without increasing the series resistance of the PeSCs. In particular, the open-circuit voltage increases from 1.06 V for the PeSC with MPS2-TMA to 1.11 V for the PeSC with MPS6-TMA. The trap densities of the PeSCs with MPS2,4,6-TMA are further analyzed using frequency-dependent capacitance measurements. Finally, a large-area (1 cm(2)) PeSC is successfully fabricated with MPS6-TMA, showing a power conversion efficiency of 18.38% with negligible hysteresis and a stable power output under light soaking for 60 s. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | HALIDE PEROVSKITES | - |
dc.subject | BAND-GAP | - |
dc.subject | PASSIVATION | - |
dc.subject | PERFORMANCE | - |
dc.subject | LIGHT | - |
dc.title | Multiply Charged Conjugated Polyelectrolytes as a Multifunctional Interlayer for Efficient and Scalable Perovskite Solar Cells | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Woo, Han Young | - |
dc.identifier.doi | 10.1002/adma.202002333 | - |
dc.identifier.scopusid | 2-s2.0-85087145060 | - |
dc.identifier.wosid | 000541471200001 | - |
dc.identifier.bibliographicCitation | ADVANCED MATERIALS, v.32, no.30 | - |
dc.relation.isPartOf | ADVANCED MATERIALS | - |
dc.citation.title | ADVANCED MATERIALS | - |
dc.citation.volume | 32 | - |
dc.citation.number | 30 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | HALIDE PEROVSKITES | - |
dc.subject.keywordPlus | BAND-GAP | - |
dc.subject.keywordPlus | PASSIVATION | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | LIGHT | - |
dc.subject.keywordAuthor | conjugated polyelectrolytes | - |
dc.subject.keywordAuthor | defect passivation | - |
dc.subject.keywordAuthor | perovskites | - |
dc.subject.keywordAuthor | scalability | - |
dc.subject.keywordAuthor | solar cells | - |
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