Molecular Ordering Behavior of Lyotropic Chromonic Liquid Crystals on a Polyimide Alignment Layer

Abstract

Coating-type polarizing films with a high dichroic ratio (DR) and polarization efficiency in the visible region were fabricated using a solution of ternary lyotropic chromonic liquid crystals (LCLCs). Optical characteristics of these anisotropic LCLC polarizing films were then determined. DR increased with increasing LCLC concentrations. Molecular ordering of these LCLCs on a rubbed polyimide (PI) layer increased because LCLC molecules' orientation was enhanced by the dielectric anisotropy effect from rubbing the surface of the PI. In addition, this study demonstrated how the interaction between liquid crystal aggregates and the PI surface with different LCLC solutions correlated with LCLC molecular orientations on the PI which is significantly dependent on whether the coating direction of the LCLC solution was parallel or perpendicular to the PI rubbing direction. It was found that the ordering direction at high LCLC concentrations was determined by shearing direction of the LCLC solution coating, whereas the ordering direction at low LCLC concentrations was governed by the dielectric anisotropy effect from the PI rubbing direction.