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Organocatalytic Asymmetric Michael Addition of Ketones to alpha,beta-Unsaturated Nitro Compounds

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dc.contributor.authorShim, Jae Ho-
dc.contributor.authorNam, Si Hun-
dc.contributor.authorKim, Byeong-Seon-
dc.contributor.authorHa, Deok-Chan-
dc.date.accessioned2021-08-30T22:14:06Z-
dc.date.available2021-08-30T22:14:06Z-
dc.date.created2021-06-19-
dc.date.issued2020-06-
dc.identifier.issn2073-4344-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/55459-
dc.description.abstractAn organic catalyst "(R,R)-1,2-diphenylethylenediamine(DPEN) derivative'' was devel-oped as a chiral bifunctional organocatalyst and applied for asymmetric Michael additions of aromatic ketones totrans-beta-nitroalkene compounds under neutral conditions. The isopropyl-subs-tituted thiourea catalyst in neutral condition provides high chemical yield and enantioselectivities (ee) (up to 96% yield, 98% ee).-
dc.languageEnglish-
dc.language.isoen-
dc.publisherMDPI-
dc.subjectCONJUGATE ADDITION-
dc.subjectAROMATIC KETONES-
dc.subjectCATALYSTS-
dc.subjectENANTIOMERS-
dc.subjectAMINES-
dc.subjectDONORS-
dc.titleOrganocatalytic Asymmetric Michael Addition of Ketones to alpha,beta-Unsaturated Nitro Compounds-
dc.typeArticle-
dc.contributor.affiliatedAuthorShim, Jae Ho-
dc.contributor.affiliatedAuthorHa, Deok-Chan-
dc.identifier.doi10.3390/catal10060618-
dc.identifier.scopusid2-s2.0-85088802562-
dc.identifier.wosid000554706300001-
dc.identifier.bibliographicCitationCATALYSTS, v.10, no.6-
dc.relation.isPartOfCATALYSTS-
dc.citation.titleCATALYSTS-
dc.citation.volume10-
dc.citation.number6-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.subject.keywordPlusCONJUGATE ADDITION-
dc.subject.keywordPlusAROMATIC KETONES-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusENANTIOMERS-
dc.subject.keywordPlusAMINES-
dc.subject.keywordPlusDONORS-
dc.subject.keywordAuthororganocatalyst-
dc.subject.keywordAuthorenantioselectivity-
dc.subject.keywordAuthoryield-
dc.subject.keywordAuthorthiourea catalyst-
dc.subject.keywordAuthorasymmetric-
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