Mechanical Force Induces Ylide-Free Cycloaddition of Nonscissible Aziridines
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jung, Sangmin | - |
dc.contributor.author | Yoon, Hyo Jae | - |
dc.date.accessioned | 2021-08-31T06:24:01Z | - |
dc.date.available | 2021-08-31T06:24:01Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2020-03-16 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/57262 | - |
dc.description.abstract | The application of aziridines as nonvulnerable mechanophores is reported. Upon exposure to a mechanical force, stereochemically pure nonactivated aziridines incorporated into the backbone of a macromolecule do not undergo cis-trans isomerization, thus suggesting retention of the ring structure under force. Nonetheless, aziridines react with a dipolarophile and seem not to obey conventional reaction pathways that involve C-C or C-N bond cleavage prior to the cycloaddition. Our work demonstrates that a nonvulnerable chemical structure can be a mechanophore. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | COVALENT BONDS | - |
dc.subject | POLYMER | - |
dc.subject | ACTIVATION | - |
dc.subject | MECHANOCHEMISTRY | - |
dc.subject | REACTIVITY | - |
dc.title | Mechanical Force Induces Ylide-Free Cycloaddition of Nonscissible Aziridines | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yoon, Hyo Jae | - |
dc.identifier.doi | 10.1002/anie.201915438 | - |
dc.identifier.scopusid | 2-s2.0-85078880389 | - |
dc.identifier.wosid | 000510543200001 | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.59, no.12, pp.4883 - 4887 | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 59 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 4883 | - |
dc.citation.endPage | 4887 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | COVALENT BONDS | - |
dc.subject.keywordPlus | POLYMER | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | MECHANOCHEMISTRY | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordAuthor | aziridines | - |
dc.subject.keywordAuthor | cycloaddition | - |
dc.subject.keywordAuthor | mechanochemistry | - |
dc.subject.keywordAuthor | mechanophores | - |
dc.subject.keywordAuthor | stereoselectivity | - |
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