Metalloporphyrinic metal-organic frameworks: Controlled synthesis for catalytic applications in environmental and biological media
DC Field | Value | Language |
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dc.contributor.author | Younis, Sherif A. | - |
dc.contributor.author | Lim, Dong-Kwon | - |
dc.contributor.author | Kim, Ki-Hyun | - |
dc.contributor.author | Deep, Akash | - |
dc.date.accessioned | 2021-08-31T08:44:33Z | - |
dc.date.available | 2021-08-31T08:44:33Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2020-03 | - |
dc.identifier.issn | 0001-8686 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/57450 | - |
dc.description.abstract | Recently, as a new sub-family of porous coordination polymers (PCPs), porphyrinic-MOFs (Porph-MOFs) with biomimetic features have been developed using porphyrin macrocycles as ligands and/or pillared linkers. The control over the coordination of the porphyrin ligand and its derivatives however remains a challenge for engineering new tunable Porph-MOF frameworks by self-assembly methods. The key challenges exist in the following respects: (i) collapse of the large open pores of Porph-MOFs during synthesis, (ii) deactivation of unsaturated metal-sites (UMCs) by axial coordination, and (iii) the tendency of both coordinated moieties (at peripheral meso- and beta-carbon sites) and the N-4-pyridine core to coordinate with metal cations. In this respect, this review covers the advances in the design of Porph-MOFs relative to their counterpart covalent organic frameworks (Porph-COFs). The potential utility of custom-designed porphyrin/metalloporphyrins ligands is highlighted. Synthesis strategies of Porph-MOFs are also illustrated with modular design of hybrid guest@host composites (either Porph@MOFs or guest@Porph-MOFs) with exceptional topologies and stability. This review summarizes the synergistic benefits of coordinated porphyrin ligands and functional guest molecules in Porph-MOF composites for enhanced catalytic performance in various redox applications. This review shed lights on the engineering of new tunable hetero-metals open active sites within (metallo)porphyrin-MOFs as out-of-the-box platforms for enhanced catalytic processes in chemical and biological media. (C) 2020 Elsevier B.V. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER | - |
dc.subject | INFINITE POLYMERIC FRAMEWORKS | - |
dc.subject | COBALT PORPHYRIN FRAMEWORK | - |
dc.subject | ASSISTED LINKER EXCHANGE | - |
dc.subject | SECONDARY BUILDING UNITS | - |
dc.subject | COORDINATION POLYMERS | - |
dc.subject | THIN-FILMS | - |
dc.subject | OXYGEN REDUCTION | - |
dc.subject | HETEROGENEOUS CATALYSTS | - |
dc.subject | MANGANESE PORPHYRINS | - |
dc.subject | HOMOLOGOUS SERIES | - |
dc.title | Metalloporphyrinic metal-organic frameworks: Controlled synthesis for catalytic applications in environmental and biological media | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lim, Dong-Kwon | - |
dc.identifier.doi | 10.1016/j.cis.2020.102108 | - |
dc.identifier.scopusid | 2-s2.0-85078770278 | - |
dc.identifier.wosid | 000521512600003 | - |
dc.identifier.bibliographicCitation | ADVANCES IN COLLOID AND INTERFACE SCIENCE, v.277 | - |
dc.relation.isPartOf | ADVANCES IN COLLOID AND INTERFACE SCIENCE | - |
dc.citation.title | ADVANCES IN COLLOID AND INTERFACE SCIENCE | - |
dc.citation.volume | 277 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.subject.keywordPlus | INFINITE POLYMERIC FRAMEWORKS | - |
dc.subject.keywordPlus | COBALT PORPHYRIN FRAMEWORK | - |
dc.subject.keywordPlus | ASSISTED LINKER EXCHANGE | - |
dc.subject.keywordPlus | SECONDARY BUILDING UNITS | - |
dc.subject.keywordPlus | COORDINATION POLYMERS | - |
dc.subject.keywordPlus | THIN-FILMS | - |
dc.subject.keywordPlus | OXYGEN REDUCTION | - |
dc.subject.keywordPlus | HETEROGENEOUS CATALYSTS | - |
dc.subject.keywordPlus | MANGANESE PORPHYRINS | - |
dc.subject.keywordPlus | HOMOLOGOUS SERIES | - |
dc.subject.keywordAuthor | Metal-organic frameworks (MOFs) | - |
dc.subject.keywordAuthor | Metalloporphyrin coordination | - |
dc.subject.keywordAuthor | Metalloporphyrin-MOFs composites | - |
dc.subject.keywordAuthor | Modulation strategies | - |
dc.subject.keywordAuthor | Catalysis applications | - |
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