In situ preparation of Ru-N-doped template-free mesoporous carbons as a transparent counter electrode for bifacial dye-sensitized solar cells
DC Field | Value | Language |
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dc.contributor.author | Aftabuzzaman, M. | - |
dc.contributor.author | Kim, Chang Ki | - |
dc.contributor.author | Zhou, Haoran | - |
dc.contributor.author | Kim, Hwan Kyu | - |
dc.date.accessioned | 2021-08-31T12:26:29Z | - |
dc.date.available | 2021-08-31T12:26:29Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2020-01-21 | - |
dc.identifier.issn | 2040-3364 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/57975 | - |
dc.description.abstract | The development of a highly active, long-lasting, and cost-effective electrocatalyst as an alternative to platinum (Pt) is a vital issue for the commercialization of dye-sensitized solar cells. In this study, Ru-N-doped template-free mesoporous carbon (Ru-N-TMC) was prepared by the direct stabilization and carbonization of the poly(butyl acrylate)-b-polyacrylonitrile (PBA-b-PAN) block copolymer and ruthenium(iii) acetylacetonate [Ru(acac)(3)]. During the stabilization process, microphase separation occurred in the PBA-b-PAN block copolymer due to the incompatibility between the two blocks, and the PAN block transformed to N-doped semi-graphitic carbon. In the carbonization step, the PBA block was eliminated as a porous template, creating hierarchal mesopores/micropores. Meanwhile, Ru(acac)(3) was decomposed to Ru, which was homogeneously distributed over the carbon substrate and anchored through N and O heteroatoms. The resulting Ru-N-TMC showed ultra-low charge transfer resistance (R-ct = 0.034 omega cm(2)) in the Co(bipyridine)(3)(3+/2+) reduction reaction, indicating very high electrocatalytic ability. Even though it is a transparent counter electrode (CE, average visible transmittance of 42.25%), covering a small fraction of the fluorine doped tin oxide (FTO)/glass substrate with Ru-N-TMC, it led to lower charge transfer resistance (R-ct = 0.55 omega cm(2)) compared to Pt (R-ct = 1.00 omega cm(2)). The Ru-N-TMC counter electrode exhibited a superior power conversion efficiency (PCE) of 11.42% compared to Pt (11.16%) when employed in SGT-021/Co(bpy)(3)(3+/2+) based dye-sensitized solar cells (DSSCs). Furthermore, a remarkable PCE of 10.13% and 8.64% from front and rear illumination, respectively, was obtained when the Ru-N-TMC counter electrode was employed in a bifacial DSSC. The outstanding catalytic activity and PCE of Ru-N-TMC were due to the high surface area of Ru-N-TMC, which contained numerous active species (Ru and N), easily facilitated to redox ions through the hierarchical microporous/mesoporous structure. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | PLATINUM NANOPARTICLES | - |
dc.subject | HIGHLY TRANSPARENT | - |
dc.subject | LOW-COST | - |
dc.subject | EFFICIENCY | - |
dc.subject | GRAPHENE | - |
dc.subject | PERFORMANCE | - |
dc.subject | NANOFIBERS | - |
dc.subject | CHALLENGES | - |
dc.subject | COMPOSITE | - |
dc.subject | LIGNIN | - |
dc.title | In situ preparation of Ru-N-doped template-free mesoporous carbons as a transparent counter electrode for bifacial dye-sensitized solar cells | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Hwan Kyu | - |
dc.identifier.doi | 10.1039/c9nr09019c | - |
dc.identifier.scopusid | 2-s2.0-85078376601 | - |
dc.identifier.wosid | 000509545700033 | - |
dc.identifier.bibliographicCitation | NANOSCALE, v.12, no.3, pp.1602 - 1616 | - |
dc.relation.isPartOf | NANOSCALE | - |
dc.citation.title | NANOSCALE | - |
dc.citation.volume | 12 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 1602 | - |
dc.citation.endPage | 1616 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.subject.keywordPlus | PLATINUM NANOPARTICLES | - |
dc.subject.keywordPlus | HIGHLY TRANSPARENT | - |
dc.subject.keywordPlus | LOW-COST | - |
dc.subject.keywordPlus | EFFICIENCY | - |
dc.subject.keywordPlus | GRAPHENE | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | NANOFIBERS | - |
dc.subject.keywordPlus | CHALLENGES | - |
dc.subject.keywordPlus | COMPOSITE | - |
dc.subject.keywordPlus | LIGNIN | - |
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