Regulating lithium nucleation and growth by zinc modified current collectors
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhang, Na | - |
dc.contributor.author | Yu, Seung-Ho | - |
dc.contributor.author | Abruna, Hector D. | - |
dc.date.accessioned | 2021-08-31T15:05:52Z | - |
dc.date.available | 2021-08-31T15:05:52Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2020-01 | - |
dc.identifier.issn | 1998-0124 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/58507 | - |
dc.description.abstract | Lithium metal is commonly regarded as the "Holy Grail" anode material for high energy density rechargeable batteries. However, the uncontrollable growth of Li dendrites has posed safety concerns and thus greatly hindered its large-scale application. Here we have modified the surface of a commercial anode current collector, Cu foil, with a thin layer of Zn by a facile electroplating method, in order to regulate the Li nucleation and the following growth processes. Because of the formation of a solid solution buffer layer and Li-Zn alloy phases, the Li nucleation overpotential was dramatically reduced, realizing a uniform Li nucleation and a smooth Li plating morphology. As a result, significantly improved long-term cycling performance with a high Coulombic efficiency was achieved by the lithiophilic Zn coated Cu foil as a current collector. Full cells of Li-LiFePO4 and Li-S using the Li deposited on the Zn modified Cu as the anode, showed increased capacity with low voltage hysteresis and greatly enhanced cycling stability, ascribed to the uniform Li deposition and formation of a stable SEI layer. This work demonstrates the feasibility of employing lithiophilic modified Cu foils as Li metal current collectors for practical applications. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | TSINGHUA UNIV PRESS | - |
dc.subject | INTERFACIAL LAYER | - |
dc.subject | METAL ANODES | - |
dc.subject | ELECTROLYTES | - |
dc.subject | ELECTRODES | - |
dc.subject | DEPOSITION | - |
dc.subject | ENCAPSULATION | - |
dc.subject | MECHANISM | - |
dc.subject | BEHAVIOR | - |
dc.subject | NITRATE | - |
dc.subject | IMPACT | - |
dc.title | Regulating lithium nucleation and growth by zinc modified current collectors | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yu, Seung-Ho | - |
dc.identifier.doi | 10.1007/s12274-019-2567-7 | - |
dc.identifier.scopusid | 2-s2.0-85075622453 | - |
dc.identifier.wosid | 000511896800004 | - |
dc.identifier.bibliographicCitation | NANO RESEARCH, v.13, no.1, pp.45 - 51 | - |
dc.relation.isPartOf | NANO RESEARCH | - |
dc.citation.title | NANO RESEARCH | - |
dc.citation.volume | 13 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 45 | - |
dc.citation.endPage | 51 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.subject.keywordPlus | INTERFACIAL LAYER | - |
dc.subject.keywordPlus | METAL ANODES | - |
dc.subject.keywordPlus | ELECTROLYTES | - |
dc.subject.keywordPlus | ELECTRODES | - |
dc.subject.keywordPlus | DEPOSITION | - |
dc.subject.keywordPlus | ENCAPSULATION | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordPlus | NITRATE | - |
dc.subject.keywordPlus | IMPACT | - |
dc.subject.keywordAuthor | lithium metal anode | - |
dc.subject.keywordAuthor | lithium dendrite | - |
dc.subject.keywordAuthor | current collector | - |
dc.subject.keywordAuthor | zinc layer | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.