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Enhanced Controllability of Fries Rearrangements Using High-Resolution 3D-Printed Metal Microreactor with Circular Channel

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dc.contributor.authorLee, Hyune-Jea-
dc.contributor.authorRoberts, Robert C.-
dc.contributor.authorIm, Do Jin-
dc.contributor.authorYim, Se-Jun-
dc.contributor.authorKim, Heejin-
dc.contributor.authorKim, Ji Tae-
dc.contributor.authorKim, Dong-Pyo-
dc.date.accessioned2021-08-31T20:24:30Z-
dc.date.available2021-08-31T20:24:30Z-
dc.date.created2021-06-18-
dc.date.issued2019-12-13-
dc.identifier.issn1613-6810-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/60924-
dc.description.abstractHigh-resolution 3D-printed stainless steel metal microreactors (3D-PMRs) with different cross-sectional geometry are fabricated to control ultrafast intramolecular rearrangement reactions in a comparative manner. The 3D-PMR with circular channel demonstrates the improved controllability in rapid Fries-type rearrangement reactions, because of the superior mixing efficiency to rectangular cross-section channels (250 mu m x 125 mu m) which is confirmed based on the computational flow dynamics simulation. Even in case of very rapid intramolecular rearrangement of sterically small acetyl group occurring in 333 mu s of reaction time, the desired intermolecular reaction can outpace to the undesired intramolecular rearrangement using 3D-PMR to result in high conversion and yield.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectCONTINUOUS-FLOW SYNTHESIS-
dc.subjectFLASH CHEMISTRY-
dc.subjectSERIAL MICROREACTIONS-
dc.subjectTECHNOLOGY-
dc.subjectBIODIESEL-
dc.subjectREACTORS-
dc.subjectDESIGN-
dc.subjectSYSTEM-
dc.subjectGREEN-
dc.titleEnhanced Controllability of Fries Rearrangements Using High-Resolution 3D-Printed Metal Microreactor with Circular Channel-
dc.typeArticle-
dc.contributor.affiliatedAuthorKim, Heejin-
dc.identifier.doi10.1002/smll.201905005-
dc.identifier.scopusid2-s2.0-85075190452-
dc.identifier.wosid000496535900001-
dc.identifier.bibliographicCitationSMALL, v.15, no.50-
dc.relation.isPartOfSMALL-
dc.citation.titleSMALL-
dc.citation.volume15-
dc.citation.number50-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaScience & Technology - Other Topics-
dc.relation.journalResearchAreaMaterials Science-
dc.relation.journalResearchAreaPhysics-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryNanoscience & Nanotechnology-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryPhysics, Applied-
dc.relation.journalWebOfScienceCategoryPhysics, Condensed Matter-
dc.subject.keywordPlusCONTINUOUS-FLOW SYNTHESIS-
dc.subject.keywordPlusFLASH CHEMISTRY-
dc.subject.keywordPlusSERIAL MICROREACTIONS-
dc.subject.keywordPlusTECHNOLOGY-
dc.subject.keywordPlusBIODIESEL-
dc.subject.keywordPlusREACTORS-
dc.subject.keywordPlusDESIGN-
dc.subject.keywordPlusSYSTEM-
dc.subject.keywordPlusGREEN-
dc.subject.keywordAuthor3D print-
dc.subject.keywordAuthorflow chemistry-
dc.subject.keywordAuthorFries rearrangement-
dc.subject.keywordAuthormicroreactors-
dc.subject.keywordAuthorreactive intermediates-
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