Enhanced Controllability of Fries Rearrangements Using High-Resolution 3D-Printed Metal Microreactor with Circular Channel
DC Field | Value | Language |
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dc.contributor.author | Lee, Hyune-Jea | - |
dc.contributor.author | Roberts, Robert C. | - |
dc.contributor.author | Im, Do Jin | - |
dc.contributor.author | Yim, Se-Jun | - |
dc.contributor.author | Kim, Heejin | - |
dc.contributor.author | Kim, Ji Tae | - |
dc.contributor.author | Kim, Dong-Pyo | - |
dc.date.accessioned | 2021-08-31T20:24:30Z | - |
dc.date.available | 2021-08-31T20:24:30Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2019-12-13 | - |
dc.identifier.issn | 1613-6810 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/60924 | - |
dc.description.abstract | High-resolution 3D-printed stainless steel metal microreactors (3D-PMRs) with different cross-sectional geometry are fabricated to control ultrafast intramolecular rearrangement reactions in a comparative manner. The 3D-PMR with circular channel demonstrates the improved controllability in rapid Fries-type rearrangement reactions, because of the superior mixing efficiency to rectangular cross-section channels (250 mu m x 125 mu m) which is confirmed based on the computational flow dynamics simulation. Even in case of very rapid intramolecular rearrangement of sterically small acetyl group occurring in 333 mu s of reaction time, the desired intermolecular reaction can outpace to the undesired intramolecular rearrangement using 3D-PMR to result in high conversion and yield. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | CONTINUOUS-FLOW SYNTHESIS | - |
dc.subject | FLASH CHEMISTRY | - |
dc.subject | SERIAL MICROREACTIONS | - |
dc.subject | TECHNOLOGY | - |
dc.subject | BIODIESEL | - |
dc.subject | REACTORS | - |
dc.subject | DESIGN | - |
dc.subject | SYSTEM | - |
dc.subject | GREEN | - |
dc.title | Enhanced Controllability of Fries Rearrangements Using High-Resolution 3D-Printed Metal Microreactor with Circular Channel | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Heejin | - |
dc.identifier.doi | 10.1002/smll.201905005 | - |
dc.identifier.scopusid | 2-s2.0-85075190452 | - |
dc.identifier.wosid | 000496535900001 | - |
dc.identifier.bibliographicCitation | SMALL, v.15, no.50 | - |
dc.relation.isPartOf | SMALL | - |
dc.citation.title | SMALL | - |
dc.citation.volume | 15 | - |
dc.citation.number | 50 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | CONTINUOUS-FLOW SYNTHESIS | - |
dc.subject.keywordPlus | FLASH CHEMISTRY | - |
dc.subject.keywordPlus | SERIAL MICROREACTIONS | - |
dc.subject.keywordPlus | TECHNOLOGY | - |
dc.subject.keywordPlus | BIODIESEL | - |
dc.subject.keywordPlus | REACTORS | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | SYSTEM | - |
dc.subject.keywordPlus | GREEN | - |
dc.subject.keywordAuthor | 3D print | - |
dc.subject.keywordAuthor | flow chemistry | - |
dc.subject.keywordAuthor | Fries rearrangement | - |
dc.subject.keywordAuthor | microreactors | - |
dc.subject.keywordAuthor | reactive intermediates | - |
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