Selection of Neighboring Group Participation Intermediates of Fully Acylated Donors around the Glycosylation Sites in Oligosaccharide Acceptors
DC Field | Value | Language |
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dc.contributor.author | Son, Sang-Hyun | - |
dc.contributor.author | Byun, Youngjoo | - |
dc.contributor.author | Sakairi, Nobuo | - |
dc.date.accessioned | 2021-08-31T21:24:16Z | - |
dc.date.available | 2021-08-31T21:24:16Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2019-12-06 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/60945 | - |
dc.description.abstract | Stereo- and regioselective formation of glycosidic linkages is a challenging topic in oligosaccharide syntheses. The stereoselective construction of 1,2-trans-glycosides generally involves neighboring group participation, which is less successful when synthesizing beta-1,3-linked oligosaccharides. The combined steric effect of a 2-O-substituent and an aglycon moiety in acceptors increases the efficiency of glycosylation via neighboring group participation. This steric effect was reduced by using vicinal polyol acceptors and was demonstrated in the synthesis of 1,3-linked branched oligosaccharides. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Selection of Neighboring Group Participation Intermediates of Fully Acylated Donors around the Glycosylation Sites in Oligosaccharide Acceptors | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Byun, Youngjoo | - |
dc.identifier.doi | 10.1021/acs.orglett.9b03601 | - |
dc.identifier.scopusid | 2-s2.0-85075137813 | - |
dc.identifier.wosid | 000502163300019 | - |
dc.identifier.bibliographicCitation | ORGANIC LETTERS, v.21, no.23, pp.9368 - 9371 | - |
dc.relation.isPartOf | ORGANIC LETTERS | - |
dc.citation.title | ORGANIC LETTERS | - |
dc.citation.volume | 21 | - |
dc.citation.number | 23 | - |
dc.citation.startPage | 9368 | - |
dc.citation.endPage | 9371 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
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