Blue Phosphorescence with High Quantum Efficiency Engaging the Trifluoromethylsulfonyl Group to Iridium Phenylpyridine Complexes
DC Field | Value | Language |
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dc.contributor.author | Kim, Jin-Hyoung | - |
dc.contributor.author | Kim, So-Yoen | - |
dc.contributor.author | Jang, Seol | - |
dc.contributor.author | Yi, Seungjun | - |
dc.contributor.author | Cho, Dae Won | - |
dc.contributor.author | Son, Ho-Jin | - |
dc.contributor.author | Kang, Sang Ook | - |
dc.date.accessioned | 2021-08-31T22:06:47Z | - |
dc.date.available | 2021-08-31T22:06:47Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2019-12-02 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/60965 | - |
dc.description.abstract | Incorporation of an electron-withdrawing -SO2CF3 substituent to cyclometalating C<^>N-phenylpyridine (ppy) ligand resulted in an expected blue-shifted phosphorescence in the corresponding homoleptic Ir(ppySCF(3))(3) complex, showing the emission of lambda(em) = 464 nm at 300 K. One of its heteroleptic derivatives, modified by a pyrazolyl borate LX ligand, Ir(ppySCF(3))(2)(bor), exhibited further blue-shifted phosphorescence of lambda(em) = 460 nm at 300 K. Cyclic voltammograms (CVs) and density-functional theory (DFT) calculations supported the efficacy of the electron-withdrawing capability of the SO2CF3 substituent lowering HOMO energy and obtained widened bandgaps and resumed blue emissions for all of the iridium complexes studied. The homoleptic complexes of both substituents, Ir(ppySCF(3))(3) and Ir(ppySF)(3), reached the higher quantum yields (Phi(PL)) of (0.89 and 0.72), respectively. Similarly, emission quantum yields (Phi(PL)) of the heteroleptic derivatives were reported to be (0.75, 0.83, and 0.87) for Ir(ppySCF(3))(2)(acac), Ir(ppySCF(3))(2)(bor), and Ir(ppySCF(3))(2)(pic), respectively. Emission kinetics support the enhanced quantum efficiency when k(r) and k(nr) values are compared between Ir(ppySCF(3))(3) and Ir(ppySF)(3), and both values favorably contribute to attaining a higher quantum efficiency for Ir(ppySCF(3))(3). Among solution-processed multilayered devices having an ITO/PEDOT:PSS/TCTA:Ir dopant (10:1, w/w)/TmPyPB/Liq/Al structure, a heteroleptic dopant, Ir(ppySCF(3))(2)(bor), exhibited better device performance, reporting an external quantum efficiency (EQE) of 1.14%, current efficiency (CE) of 2.31 cd A(-1), and power efficiency (PE) of 1.21 lm W-1, together with blue chromaticity of CIEx,y = (0.16, 0.32). | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | CYCLOMETALATED IR(III) COMPLEXES | - |
dc.subject | ORGANIC ELECTROPHOSPHORESCENCE | - |
dc.subject | SULFONYL | - |
dc.subject | GREEN | - |
dc.subject | EMISSION | - |
dc.subject | COLOR | - |
dc.subject | EMITTERS | - |
dc.subject | LIGANDS | - |
dc.subject | STATES | - |
dc.subject | OLEDS | - |
dc.title | Blue Phosphorescence with High Quantum Efficiency Engaging the Trifluoromethylsulfonyl Group to Iridium Phenylpyridine Complexes | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Cho, Dae Won | - |
dc.contributor.affiliatedAuthor | Son, Ho-Jin | - |
dc.contributor.affiliatedAuthor | Kang, Sang Ook | - |
dc.identifier.doi | 10.1021/acs.inorgchem.9b02672 | - |
dc.identifier.scopusid | 2-s2.0-85075957999 | - |
dc.identifier.wosid | 000500650600045 | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.58, no.23, pp.16112 - 16125 | - |
dc.relation.isPartOf | INORGANIC CHEMISTRY | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 58 | - |
dc.citation.number | 23 | - |
dc.citation.startPage | 16112 | - |
dc.citation.endPage | 16125 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.subject.keywordPlus | CYCLOMETALATED IR(III) COMPLEXES | - |
dc.subject.keywordPlus | ORGANIC ELECTROPHOSPHORESCENCE | - |
dc.subject.keywordPlus | SULFONYL | - |
dc.subject.keywordPlus | GREEN | - |
dc.subject.keywordPlus | EMISSION | - |
dc.subject.keywordPlus | COLOR | - |
dc.subject.keywordPlus | EMITTERS | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | STATES | - |
dc.subject.keywordPlus | OLEDS | - |
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