Control of the Metal Composition in Bimetallic Mg/Zn(dobpdc) Constructed from a One-Dimensional Zn-Based Template
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Hyojin | - |
dc.contributor.author | Lee, Hwa Young | - |
dc.contributor.author | Kang, Dong Won | - |
dc.contributor.author | Kang, Minjung | - |
dc.contributor.author | Choe, Jong Hyeak | - |
dc.contributor.author | Lee, Woo Ram | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.date.accessioned | 2021-09-01T01:54:31Z | - |
dc.date.available | 2021-09-01T01:54:31Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2019-10-21 | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/62186 | - |
dc.description.abstract | While mixed-metal ions into a single framework can be randomly arranged in most reported cases, it is synthetically challenging to control and organize the distribution of different metal ions over a three-dimensional structure. In this context, for the family of M-2(dobpdc) with broad applications, we present the first case of a bimetallic Mg/Zn(dobpdc) framework with a 1:1 compositional ratio, based on a one-dimensional Zn(H(2)dobpdc) template, which would not be obtained by the conventional reaction of the corresponding metal salts. Moreover, we demonstrate that the resultant compositional ratios in the bimetallic M'/Zn(dobpdc) (M' = Mg, Mn, Co, Ni) are governed by the ionic radii of the metals and the affinity of the metal ions for the linker groups. Notably, the unexpected gradual reduction in the adsorption enthalpy and the mixed CO, adsorption feature are revealed in Mg/Zn(dobpdc) and its diamine-grafted framework, respectively. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | DIOXIDE CAPTURE CAPABILITY | - |
dc.subject | ORGANIC FRAMEWORK | - |
dc.subject | MIXED-METAL | - |
dc.subject | CARBON-DIOXIDE | - |
dc.subject | FLUE-GAS | - |
dc.subject | CO2 ADSORPTION | - |
dc.subject | OXIDATION | - |
dc.subject | MOF-5 | - |
dc.subject | SUBSTITUTION | - |
dc.subject | INSERTION | - |
dc.title | Control of the Metal Composition in Bimetallic Mg/Zn(dobpdc) Constructed from a One-Dimensional Zn-Based Template | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Hong, Chang Seop | - |
dc.identifier.doi | 10.1021/acs.inorgchem.9b02126 | - |
dc.identifier.scopusid | 2-s2.0-85073123400 | - |
dc.identifier.wosid | 000492117900059 | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.58, no.20, pp.14107 - 14111 | - |
dc.relation.isPartOf | INORGANIC CHEMISTRY | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 58 | - |
dc.citation.number | 20 | - |
dc.citation.startPage | 14107 | - |
dc.citation.endPage | 14111 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.subject.keywordPlus | DIOXIDE CAPTURE CAPABILITY | - |
dc.subject.keywordPlus | ORGANIC FRAMEWORK | - |
dc.subject.keywordPlus | MIXED-METAL | - |
dc.subject.keywordPlus | CARBON-DIOXIDE | - |
dc.subject.keywordPlus | FLUE-GAS | - |
dc.subject.keywordPlus | CO2 ADSORPTION | - |
dc.subject.keywordPlus | OXIDATION | - |
dc.subject.keywordPlus | MOF-5 | - |
dc.subject.keywordPlus | SUBSTITUTION | - |
dc.subject.keywordPlus | INSERTION | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.