In situ self-assembly of Ni3S2/MnS/CuS/reduced graphene composite on nickel foam for high power supercapacitors
DC Field | Value | Language |
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dc.contributor.author | Li, Wenbo | - |
dc.contributor.author | Song, Weiming | - |
dc.contributor.author | Wang, Haihua | - |
dc.contributor.author | Kang, Yong-Mook | - |
dc.date.accessioned | 2021-09-01T04:24:44Z | - |
dc.date.available | 2021-09-01T04:24:44Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2019-10-07 | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/62539 | - |
dc.description.abstract | Transition metal sulfides (TMS), as promising electroactive materials for asymmetric supercapacitors, have been limited due to their relatively poor conductivity and cycle stability. Here ternary Ni3S2/MnS/CuS composites were assembled in situ on nickel foam (NF) using a hydrothermal method via electrostatic adsorption of Ni+, Mn2+ and Cu2+ ions on a reduced graphene (rGO) nanosheet template. The chemical structure was characterized by various analytic methods. Ni3S2/MnS/CuS has spherical morphology assembled from closely packed nanosheets, while Ni3S2/MnS/CuS@rGO has a three-dimensional porous spherical structure with much lower diameter because rGO nanosheets can play the role of a template to induce the growth of Ni3S2/MnS/CuS. At a current density of 1 A g(-1), the specific capacitance was obtained to be 1028 F g(-1) for Ni3S2/MnS/CuS, 628.6 F g(-1) for Ni3S2/MnS@rGO, and 2042 F g(-1) for Ni3S2/MnS/CuS@rGO, respectively. Charge transfer resistance (R-ct) of Ni3S2/MnS/CuS@rGO (0.001 omega) was much lower than that of Ni3S2/MnS@rGO by 0.02 omega, and lower than that of Ni3S2/MnS/CuS by 0.017 omega. After 5000 cycles, the Ni3S2-MnS-CuS@RGO electrode maintains 78.3% of the initial capacity at 20 A g(-1). An asymmetric supercapacitor was subsequently assembled using Ni3S2/MnS/CuS@rGO as the positive electrode and rGO as the negative electrode. The specific capacitance of asymmetric batteries was maintained at 90.8% of the initial state after 5000 GCD. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | HIGH-PERFORMANCE SUPERCAPACITOR | - |
dc.subject | ELECTRODE MATERIAL | - |
dc.subject | CARBON MATERIALS | - |
dc.subject | COBALT SULFIDE | - |
dc.subject | METAL SULFIDES | - |
dc.subject | NI FOAM | - |
dc.subject | NANOPARTICLES | - |
dc.subject | CONSTRUCTION | - |
dc.subject | FABRICATION | - |
dc.subject | CATHODE | - |
dc.title | In situ self-assembly of Ni3S2/MnS/CuS/reduced graphene composite on nickel foam for high power supercapacitors | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kang, Yong-Mook | - |
dc.identifier.doi | 10.1039/c9ra05435a | - |
dc.identifier.scopusid | 2-s2.0-85073449550 | - |
dc.identifier.wosid | 000490283500038 | - |
dc.identifier.bibliographicCitation | RSC ADVANCES, v.9, no.54, pp.31532 - 31542 | - |
dc.relation.isPartOf | RSC ADVANCES | - |
dc.citation.title | RSC ADVANCES | - |
dc.citation.volume | 9 | - |
dc.citation.number | 54 | - |
dc.citation.startPage | 31532 | - |
dc.citation.endPage | 31542 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE SUPERCAPACITOR | - |
dc.subject.keywordPlus | ELECTRODE MATERIAL | - |
dc.subject.keywordPlus | CARBON MATERIALS | - |
dc.subject.keywordPlus | COBALT SULFIDE | - |
dc.subject.keywordPlus | METAL SULFIDES | - |
dc.subject.keywordPlus | NI FOAM | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | CONSTRUCTION | - |
dc.subject.keywordPlus | FABRICATION | - |
dc.subject.keywordPlus | CATHODE | - |
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