Yolk-shell-structured manganese oxide/nitride composite powders comprising cobalt-nanoparticle-embedded nitrogen-doped carbon nanotubes as cathode catalysts for long-life-cycle lithium-oxygen batteries
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Oh, Yeon Jong | - |
dc.contributor.author | Kim, Jung Hyun | - |
dc.contributor.author | Kang, Yun Chan | - |
dc.date.accessioned | 2021-09-01T04:45:53Z | - |
dc.date.available | 2021-09-01T04:45:53Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2019-10-01 | - |
dc.identifier.issn | 1385-8947 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/62571 | - |
dc.description.abstract | An air-electrode catalyst material with a hierarchically porous structure and efficient chemical composition can improve the performances of lithium-oxygen (Li-O-2) batteries. In this study, hierarchically yolk-shell structured manganese oxide/manganese nitride composite powders comprising Co-nanoparticle-embedded N-doped carbon nanotubes (yCo-NCNT-Mn) are successfully fabricated as O-2-electrode catalysts for Li-O-2 batteries. The asprepared yCo-NCNT-Mn powders exhibit high electrocatalytic activities toward both oxygen reduction and evolution. The Li-O-2 battery with yCo-NCNT-Mn exhibits a high capacity (22,344 mA h g(-1) at 200 mA g(-1)), low charge overpotential (0.25 V), and long cycling life (227 cycles at 200 mA g(-1) and cut-off capacity of 500 mA h g(-1)). Experimental analyses reveal that the improved electrochemical performance can be attributed to the synergistic advantages of the electrically conductive NCNTs and excellent catalytic activity of the bifunctional catalyst as the composite form of Co, NCNT, MnO, and Mn4N. Moreover, the unique hierarchical yolk-shell structure increases the capacity by providing a sufficient space to accommodate Li2O2. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | LAYERED DOUBLE HYDROXIDES | - |
dc.subject | ONE-STEP SYNTHESIS | - |
dc.subject | BIFUNCTIONAL CATALYSTS | - |
dc.subject | LI-O-2 BATTERIES | - |
dc.subject | EFFICIENT CATALYSIS | - |
dc.subject | EVOLUTION REACTION | - |
dc.subject | POROUS GRAPHENE | - |
dc.subject | AIR BATTERIES | - |
dc.subject | REDUCTION | - |
dc.subject | PERFORMANCE | - |
dc.title | Yolk-shell-structured manganese oxide/nitride composite powders comprising cobalt-nanoparticle-embedded nitrogen-doped carbon nanotubes as cathode catalysts for long-life-cycle lithium-oxygen batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kang, Yun Chan | - |
dc.identifier.doi | 10.1016/j.cej.2019.05.020 | - |
dc.identifier.scopusid | 2-s2.0-85065418518 | - |
dc.identifier.wosid | 000471682900008 | - |
dc.identifier.bibliographicCitation | CHEMICAL ENGINEERING JOURNAL, v.373, pp.86 - 94 | - |
dc.relation.isPartOf | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.title | CHEMICAL ENGINEERING JOURNAL | - |
dc.citation.volume | 373 | - |
dc.citation.startPage | 86 | - |
dc.citation.endPage | 94 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Engineering | - |
dc.relation.journalWebOfScienceCategory | Engineering, Environmental | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.subject.keywordPlus | LAYERED DOUBLE HYDROXIDES | - |
dc.subject.keywordPlus | ONE-STEP SYNTHESIS | - |
dc.subject.keywordPlus | BIFUNCTIONAL CATALYSTS | - |
dc.subject.keywordPlus | LI-O-2 BATTERIES | - |
dc.subject.keywordPlus | EFFICIENT CATALYSIS | - |
dc.subject.keywordPlus | EVOLUTION REACTION | - |
dc.subject.keywordPlus | POROUS GRAPHENE | - |
dc.subject.keywordPlus | AIR BATTERIES | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordAuthor | Lithium-oxygen batteries | - |
dc.subject.keywordAuthor | Hierarchical structure | - |
dc.subject.keywordAuthor | Manganese nitride | - |
dc.subject.keywordAuthor | N-doped carbon nanotubes | - |
dc.subject.keywordAuthor | Spray pyrolysis | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.