Graphite oxide- and graphene oxide-supported catalysts for microwave-assisted glucose isomerisation in water
DC Field | Value | Language |
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dc.contributor.author | Yu, Iris K. M. | - |
dc.contributor.author | Xiong, Xinni | - |
dc.contributor.author | Tsang, Daniel C. W. | - |
dc.contributor.author | Yun Hau Ng | - |
dc.contributor.author | Clark, James H. | - |
dc.contributor.author | Fan, Jiajun | - |
dc.contributor.author | Zhang, Shicheng | - |
dc.contributor.author | Hu, Changwei | - |
dc.contributor.author | Ok, Yong Sik | - |
dc.date.accessioned | 2021-09-01T08:31:01Z | - |
dc.date.available | 2021-09-01T08:31:01Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2019-08-21 | - |
dc.identifier.issn | 1463-9262 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/63490 | - |
dc.description.abstract | Graphite (G), graphite oxide (GIO), and graphene oxide (GO) were evaluated for the first time as carbon-aceous supports to synthesise heterogeneous Lewis acid catalysts, via simple AlCl3 pretreatment followed by one-step thermal modification. The GIO-and GO-supported Al catalysts were active towards catalytic isomerisation of glucose in water as the greenest solvent. The highest fructose yield of 34.6 mol% was achieved under microwave heating at 140 degrees C for 20 min. The major active sites were characterised as amorphous Al hydroxides (e.g., ss-Al(OH)(3), gamma-Al(OH)(3), and gamma-AlO(OH)) with octahedral coordination, as revealed by Al-27 NMR, XPS, SEM, TEM-EDX, Raman, ESR, and XRD analyses. The transformation of octahedral Al to pentahedral/tetrahedral coordination was observed when the activation temperature increased. Oxygen-containing functional groups on the GIO and GO surfaces, e.g., C-O-C, -OH, and -COOH, contributed to the formation of microwave-absorbing active sites. In contrast, the G-supported catalyst may contain microwave-transparent Al hydroxides, accounting for its low catalytic activity under microwave irradiation. This study elucidates the significance of the surface chemistry of carbonaceous supports in generating active species for a Lewis acid-driven reaction. The revealed intertwined relationships among modification conditions, physicochemical properties, and catalytic performance will be useful for designing effective carbon-supported catalysts for sustainable biorefinery. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | RICH FOOD WASTE | - |
dc.subject | OXYGEN FUNCTIONAL-GROUPS | - |
dc.subject | LEVULINIC ACID | - |
dc.subject | HYDROXYMETHYLFURFURAL HMF | - |
dc.subject | GAMMA-VALEROLACTONE | - |
dc.subject | TRANSFER HYDROGENATION | - |
dc.subject | WOOD BIOCHAR | - |
dc.subject | DUAL ROLE | - |
dc.subject | VALORIZATION | - |
dc.subject | CONVERSION | - |
dc.title | Graphite oxide- and graphene oxide-supported catalysts for microwave-assisted glucose isomerisation in water | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Ok, Yong Sik | - |
dc.identifier.doi | 10.1039/c9gc00734b | - |
dc.identifier.scopusid | 2-s2.0-85070778574 | - |
dc.identifier.wosid | 000480643800031 | - |
dc.identifier.bibliographicCitation | GREEN CHEMISTRY, v.21, no.16, pp.4341 - 4353 | - |
dc.relation.isPartOf | GREEN CHEMISTRY | - |
dc.citation.title | GREEN CHEMISTRY | - |
dc.citation.volume | 21 | - |
dc.citation.number | 16 | - |
dc.citation.startPage | 4341 | - |
dc.citation.endPage | 4353 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Green & Sustainable Science & Technology | - |
dc.subject.keywordPlus | RICH FOOD WASTE | - |
dc.subject.keywordPlus | OXYGEN FUNCTIONAL-GROUPS | - |
dc.subject.keywordPlus | LEVULINIC ACID | - |
dc.subject.keywordPlus | HYDROXYMETHYLFURFURAL HMF | - |
dc.subject.keywordPlus | GAMMA-VALEROLACTONE | - |
dc.subject.keywordPlus | TRANSFER HYDROGENATION | - |
dc.subject.keywordPlus | WOOD BIOCHAR | - |
dc.subject.keywordPlus | DUAL ROLE | - |
dc.subject.keywordPlus | VALORIZATION | - |
dc.subject.keywordPlus | CONVERSION | - |
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