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Vanadium activity measurement in fcc phase Pt-V alloy

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dc.contributor.authorPark, Dong Hwi-
dc.contributor.authorJeong, Ji-Seok-
dc.contributor.authorShim, Sang-Chul-
dc.contributor.authorLee, Joonho-
dc.date.accessioned2021-09-01T13:52:50Z-
dc.date.available2021-09-01T13:52:50Z-
dc.date.created2021-06-19-
dc.date.issued2019-06-05-
dc.identifier.issn0925-8388-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/64795-
dc.description.abstractThe temperature dependence of the thermodynamic properties of V, in Pt-V alloy, was investigated in this study. A Pt strip was equilibrated with V2O3 powder, under controlled oxygen partial pressure and temperature. The mole fraction of V in the sample was measured with an electron probe micro-analyzer, and the activity coefficient of V was determined as a function of temperature and composition. With increasing temperature, the activity coefficient of V (gamma(nu)) increased. The activity coefficient at infinite dilution (gamma(0)(nu)) increased and the interaction parameter (epsilon(V)(V)) decreased with rising temperature. The excess Gibbs energy value for the fcc phase Pt-V alloy was strongly negative. (C) 2019 Elsevier B.V. All rights reserved.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherELSEVIER SCIENCE SA-
dc.subjectOXYGEN REDUCTION-
dc.subjectPLATINUM-
dc.subjectNANOPARTICLES-
dc.titleVanadium activity measurement in fcc phase Pt-V alloy-
dc.typeArticle-
dc.contributor.affiliatedAuthorLee, Joonho-
dc.identifier.doi10.1016/j.jallcom.2019.02.313-
dc.identifier.scopusid2-s2.0-85062418024-
dc.identifier.wosid000462767000112-
dc.identifier.bibliographicCitationJOURNAL OF ALLOYS AND COMPOUNDS, v.788, pp.967 - 971-
dc.relation.isPartOfJOURNAL OF ALLOYS AND COMPOUNDS-
dc.citation.titleJOURNAL OF ALLOYS AND COMPOUNDS-
dc.citation.volume788-
dc.citation.startPage967-
dc.citation.endPage971-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaMaterials Science-
dc.relation.journalResearchAreaMetallurgy & Metallurgical Engineering-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.relation.journalWebOfScienceCategoryMetallurgy & Metallurgical Engineering-
dc.subject.keywordPlusOXYGEN REDUCTION-
dc.subject.keywordPlusPLATINUM-
dc.subject.keywordPlusNANOPARTICLES-
dc.subject.keywordAuthorActivity coefficient-
dc.subject.keywordAuthorExcess Gibbs energy-
dc.subject.keywordAuthorPt-V alloy-
dc.subject.keywordAuthorThermodynamics-
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