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Discriminative detection of indoor volatile organic compounds using a sensor array based on pure and Fe-doped In2O3 nanofibers

Authors
Lee, Chul-SoonLi, Hua-YaoKim, Bo-YoungJo, Young-MooByun, Hyung-GiHwang, In-SungAbdel-Hady, FaissalWazzan, Abdulaziz A.Lee, Jong-Heun
Issue Date
15-4월-2019
Publisher
ELSEVIER SCIENCE SA
Keywords
Gas sensor; Oxide semiconductor; In2O3; Volatile organic compound; Indoor air quality
Citation
SENSORS AND ACTUATORS B-CHEMICAL, v.285, pp.193 - 200
Indexed
SCIE
SCOPUS
Journal Title
SENSORS AND ACTUATORS B-CHEMICAL
Volume
285
Start Page
193
End Page
200
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/65996
DOI
10.1016/j.snb.2019.01.044
ISSN
0925-4005
Abstract
Representative indoor volatile organic compounds (VOCs) such as benzene, xylene, toluene, formaldehyde, and ethanol need to be detected in a highly sensitive and discriminative manner because of their different impact on human health. In this study, pure and 0.05, 0.1, 0.3, and 0.5 at% Fe-doped In2O3 nanofibers were prepared by electrospinning and their gas sensing characteristics toward the aforementioned VOCs were investigated. The doping of In2O3 nanofiber sensor with 0.05 and 0.1 at% Fe shifted the temperature to show the maximum responses to benzene, xylene, and toluene, and reduced responses to ethanol and formaldehyde, thus demonstrating changed gas selectivity. The gas sensing characteristics of 0.5 at% Fe-doped In2O3 nanofiber sensor were substantially different from those of the other sensors. Significantly different gas sensing patterns of pure and Fe-doped In2O3 sensors could be used to discriminate between the five different VOCs at 375 degrees C and to distinguish between the aromatic and non-aromatic gases at all sensing temperatures. The mechanism underlying the Fe-induced change in gas sensing characteristics has been discussed in relation to the variation of catalytic activity, morphology, oxygen adsorption, and charge carrier concentration.
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