Synthesis of benzo[a]carbazoles via cyanide-catalyzed imino-Stetter reaction/Friedel-Crafts reaction sequence
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Jeon, Jiye | - |
dc.contributor.author | Cheon, Cheol-Hong | - |
dc.date.accessioned | 2021-09-01T18:58:08Z | - |
dc.date.available | 2021-09-01T18:58:08Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2019-02-21 | - |
dc.identifier.issn | 2052-4110 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/67600 | - |
dc.description.abstract | A new protocol to access benzo[a] carbazole derivatives was developed, via the cyanide-catalyzed iminoStetter reaction/ Friedel-Crafts reaction sequence. The cyanide-catalyzed imino-Stetter reaction of aldimines derived from 2-aminochalcones and aromatic aldehydes provided the corresponding 2-aryl-3-arenacylindole derivatives, which could be converted to benzo[a] carbazoles via intramolecular Friedel-Crafts ractions. Various 2-aminochalcones and aldehydes were applicable to this protocol, affording the desired benzo[a] carbazoles in good to high yields. Furthermore, we also developed a sequential protocol for the construction of benzo[a] carbazoles from 2-aminochalcones and aldehydes, without isolating any intermediates. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | BIOLOGICAL EVALUATION | - |
dc.subject | CONCISE SYNTHESIS | - |
dc.subject | DERIVATIVES | - |
dc.subject | CYCLIZATION | - |
dc.subject | DESIGN | - |
dc.subject | CARBAZOLES | - |
dc.subject | ANNULATION | - |
dc.subject | ARYLATION | - |
dc.subject | ACCESS | - |
dc.title | Synthesis of benzo[a]carbazoles via cyanide-catalyzed imino-Stetter reaction/Friedel-Crafts reaction sequence | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Cheon, Cheol-Hong | - |
dc.identifier.doi | 10.1039/c8qo01209a | - |
dc.identifier.scopusid | 2-s2.0-85061523011 | - |
dc.identifier.wosid | 000458518400005 | - |
dc.identifier.bibliographicCitation | ORGANIC CHEMISTRY FRONTIERS, v.6, no.4, pp.456 - 467 | - |
dc.relation.isPartOf | ORGANIC CHEMISTRY FRONTIERS | - |
dc.citation.title | ORGANIC CHEMISTRY FRONTIERS | - |
dc.citation.volume | 6 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 456 | - |
dc.citation.endPage | 467 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | BIOLOGICAL EVALUATION | - |
dc.subject.keywordPlus | CONCISE SYNTHESIS | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | CYCLIZATION | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | CARBAZOLES | - |
dc.subject.keywordPlus | ANNULATION | - |
dc.subject.keywordPlus | ARYLATION | - |
dc.subject.keywordPlus | ACCESS | - |
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