Characteristics of dual-curable blocked isocyanate with thermal radical initiator for low-temperature curing of automotive coatings
DC Field | Value | Language |
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dc.contributor.author | Jung, Kevin Injoe | - |
dc.contributor.author | Kim, Beomjin | - |
dc.contributor.author | Lee, Dong Geun | - |
dc.contributor.author | Lee, Tae-Hee | - |
dc.contributor.author | Choi, Seo Yeon | - |
dc.contributor.author | Kim, Jin Chul | - |
dc.contributor.author | Noh, Seung Man | - |
dc.contributor.author | Park, Young Il | - |
dc.contributor.author | Jung, Hyun Wook | - |
dc.date.accessioned | 2021-09-02T02:32:41Z | - |
dc.date.available | 2021-09-02T02:32:41Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2018-12 | - |
dc.identifier.issn | 0300-9440 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/71386 | - |
dc.description.abstract | Dual-curable blocked isocyanate with a thermal radical initiator (BL-Tri-cHD) was designed and synthesized to perform low-temperature curing of automotive coatings. BL-Tri-cHD can simultaneously react with both unsaturated C=C double bonds for free-radical polymerization and hydroxyl groups for the urethane reaction in hydroxyl-functionalized urethane methacrylate oligomers (HFUMO) under mild thermal curing conditions. The dual crosslinking behavior and mechanical properties of HFUMO-based coatings using BL-Tri-cHD were compared with those of a commercial blocked isocyanate thermal crosslinker (Desmodur (R) BL-PL350). The onset temperature for initiating cured by BL-Tri-cHD was about 68 degrees C, confirming faster crosslinking at relatively lower temperature than BL-PL350, which initiated curing at 140 degrees C. To quantitatively evaluate the properties of cured coatings, a nano-indentation was made in the surfaces of clearcoat films cured at 150 degrees C, 130 degrees C, and 120 degrees C. Films cured using BL-Tri-cHD and BL-PL350 at 150 degrees C exhibited similar indentation patterns. The indentation curves for the films with BL-Tri-cHD cured at lower curing temperatures such as 130 degrees C and 120 degrees C showed favorable penetration depth profiles similar to the sample cured at 150 degrees C, whereas the films with BL-PL350 cured below 150 degrees C had a less dense network structure, resulting in a deeper penetration depth than the sample cured at 150 degrees C. Therefore, we report that dual-curable BL-Tri-cHD demonstrates promising performance in automotive coating applications and possesses the ability to form highly crosslinked networks, even at low curing temperatures. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE SA | - |
dc.subject | URETHANE METHACRYLATE OLIGOMER | - |
dc.subject | O-IMINO-ISOUREA | - |
dc.subject | ELASTIC-MODULUS | - |
dc.subject | SCRATCH CHARACTERISTICS | - |
dc.subject | CROSS-LINKING | - |
dc.subject | BEHAVIOR | - |
dc.subject | POLYMER | - |
dc.subject | DISSOCIATION | - |
dc.subject | INDENTATION | - |
dc.subject | CLEARCOATS | - |
dc.title | Characteristics of dual-curable blocked isocyanate with thermal radical initiator for low-temperature curing of automotive coatings | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Jung, Hyun Wook | - |
dc.identifier.doi | 10.1016/j.porgcoat.2018.09.009 | - |
dc.identifier.scopusid | 2-s2.0-85053209962 | - |
dc.identifier.wosid | 000453642900019 | - |
dc.identifier.bibliographicCitation | PROGRESS IN ORGANIC COATINGS, v.125, pp.160 - 166 | - |
dc.relation.isPartOf | PROGRESS IN ORGANIC COATINGS | - |
dc.citation.title | PROGRESS IN ORGANIC COATINGS | - |
dc.citation.volume | 125 | - |
dc.citation.startPage | 160 | - |
dc.citation.endPage | 166 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Coatings & Films | - |
dc.subject.keywordPlus | URETHANE METHACRYLATE OLIGOMER | - |
dc.subject.keywordPlus | O-IMINO-ISOUREA | - |
dc.subject.keywordPlus | ELASTIC-MODULUS | - |
dc.subject.keywordPlus | SCRATCH CHARACTERISTICS | - |
dc.subject.keywordPlus | CROSS-LINKING | - |
dc.subject.keywordPlus | BEHAVIOR | - |
dc.subject.keywordPlus | POLYMER | - |
dc.subject.keywordPlus | DISSOCIATION | - |
dc.subject.keywordPlus | INDENTATION | - |
dc.subject.keywordPlus | CLEARCOATS | - |
dc.subject.keywordAuthor | Dual-curable blocked isocyanate | - |
dc.subject.keywordAuthor | TRI | - |
dc.subject.keywordAuthor | Low-temperature curing | - |
dc.subject.keywordAuthor | Automotive coatings | - |
dc.subject.keywordAuthor | Radical reaction | - |
dc.subject.keywordAuthor | Urethane reaction | - |
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