Naphthobistriazole-based wide bandgap donor polymers for efficient non-fullerene organic solar cells: Significant fine-tuning absorption and energy level by backbone fluorination
DC Field | Value | Language |
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dc.contributor.author | Tang, Dongsheng | - |
dc.contributor.author | Wan, Jiahui | - |
dc.contributor.author | Xu, Xiaopeng | - |
dc.contributor.author | Lee, Young Woong | - |
dc.contributor.author | Woo, Han Young | - |
dc.contributor.author | Feng, Kui | - |
dc.contributor.author | Peng, Qiang | - |
dc.date.accessioned | 2021-09-02T04:28:18Z | - |
dc.date.available | 2021-09-02T04:28:18Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2018-11 | - |
dc.identifier.issn | 2211-2855 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/72088 | - |
dc.description.abstract | In this work, two wide bandgap polymers of PDTT-TZNT and PDTF-TZNT were developed by Stille-coupling of naphtho[1,2-c:5,6-c]bis(2-octyl-[1,2,3]triazole) (TZNT) acceptor unit with bithiophene (DTH) and fluorinated bithiophene (DTF), respectively. These polymers exhibited a wide bandgap over 1.84 eV. The fluorinated PDTF-TZNT had lower highest occupied molecular orbital HOMO level (- 5.24 eV), higher molar absorption coefficient (1.28 x 10(5) M-1 cm(-1)), and higher molecular packing order. Using a low bandgap 3,9-bis(2-methylene-(5 & 6-methyl-(3-(1,1-dicyanomethylene)-indanone)))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2',3'-d']s-indaceno[1,2-b:5,6-b']-dithiophene (IT-M) as the electron acceptor, the PDTF-TZNT: IT-M devices generated a higher power conversion efficiency (PCE) of 10.05%. To make up the weak absorption of above binary blend of PDTF-TZNT:IT-M in the short wavelength region and increase the device performance further, a large bandgap small molecular acceptor of 5,5,10,10,15,15-hexabutyl-2,7,12-tri(4-(3-ethylhexyl-4-oxothiazolidine-2-yl)dimalononitrile-benzothiadiazole)- truxene (meta-TrBRCN) was added as the second acceptor material to fabricate ternary blend PSCs. The meta-TrBRCN could not only expand the absorption range but also fine-tune the blend morphology by stepwise changing its content. When 0.2 of meta-TrBRCN was added, the PCE of PDTF-TZNT:ITM devices was improved to 11.48%. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER | - |
dc.subject | POWER CONVERSION EFFICIENCY | - |
dc.subject | CONJUGATED POLYMERS | - |
dc.subject | PHOTOVOLTAIC PROPERTIES | - |
dc.subject | 13-PERCENT EFFICIENCY | - |
dc.subject | ELECTRON-ACCEPTOR | - |
dc.subject | COPOLYMERS | - |
dc.subject | UNIT | - |
dc.title | Naphthobistriazole-based wide bandgap donor polymers for efficient non-fullerene organic solar cells: Significant fine-tuning absorption and energy level by backbone fluorination | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Woo, Han Young | - |
dc.identifier.doi | 10.1016/j.nanoen.2018.08.059 | - |
dc.identifier.scopusid | 2-s2.0-85054091487 | - |
dc.identifier.wosid | 000448994600032 | - |
dc.identifier.bibliographicCitation | NANO ENERGY, v.53, pp.258 - 269 | - |
dc.relation.isPartOf | NANO ENERGY | - |
dc.citation.title | NANO ENERGY | - |
dc.citation.volume | 53 | - |
dc.citation.startPage | 258 | - |
dc.citation.endPage | 269 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.subject.keywordPlus | POWER CONVERSION EFFICIENCY | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | PHOTOVOLTAIC PROPERTIES | - |
dc.subject.keywordPlus | 13-PERCENT EFFICIENCY | - |
dc.subject.keywordPlus | ELECTRON-ACCEPTOR | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | UNIT | - |
dc.subject.keywordAuthor | Non-fullerene polymer solar cells | - |
dc.subject.keywordAuthor | Ternary blend solar cells | - |
dc.subject.keywordAuthor | Wide bandgap polymer donors | - |
dc.subject.keywordAuthor | Naphtho[1,2-c:5,6-c]bis(2-octyl-[1,2,3]triazole) | - |
dc.subject.keywordAuthor | Fluorination | - |
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