Crystal structure of {(E)-2-[(3,4-dimethoxyphenylimino)methyl]phenolato-kappa N-2,O-1}bis[2-(pyridin-2-yl)phenyl-kappa C-2(1),N]iridium(III) dichloromethane disolvate
DC Field | Value | Language |
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dc.contributor.author | Shee, Nirmal K. | - |
dc.contributor.author | Hong, Chang Seop | - |
dc.contributor.author | Lee, Woo Ram | - |
dc.contributor.author | Kim, Hee-Joon | - |
dc.date.accessioned | 2021-09-02T07:59:09Z | - |
dc.date.available | 2021-09-02T07:59:09Z | - |
dc.date.created | 2021-06-16 | - |
dc.date.issued | 2018-08 | - |
dc.identifier.issn | 2056-9890 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/73851 | - |
dc.description.abstract | The asymmetric unit of the solvated title complex, [Ir(C11H8N)(2)(C15H14NO3)]center dot 2CH(2)Cl(2), consists of two complex molecules together with four dichloromethane solvent molecules, one of which is disordered. In each complex molecule, the Ir-III ion has a distorted octahedral coordination environment defined by two 2-phenylpyridine ligands, through two phenyl C and two pyridine N atoms, and by one N,O-bidentate 2-[(2,4-dimethoxyphenylimino)methyl]phenolate anion. The Ir-III ions lie almost in the equatorial planes with deviations of 0.0396 (17) and 0.0237 (17) angstrom, respectively, for the two complex molecules. In both complex molecules, the two 2-phenylpyridine ligands are nearly perpendicular to each other [dihedral angles between the least-squares-planes of 89.91 (11) and 85.13 (11)degrees]. In the crystal, intermolecular C H center dot center dot center dot O interactions as well as intermolecular C-H center dot center dot center dot pi interactions are present, leading to a three-dimensional network structure. One of the four dichlormethane solvent molecules shows disorder over two sets of sites [occupancy ratio 0.79 (2):0.21 (2)]. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | INT UNION CRYSTALLOGRAPHY | - |
dc.subject | IRIDIUM(III) COMPLEXES | - |
dc.subject | PHOSPHORESCENCE | - |
dc.title | Crystal structure of {(E)-2-[(3,4-dimethoxyphenylimino)methyl]phenolato-kappa N-2,O-1}bis[2-(pyridin-2-yl)phenyl-kappa C-2(1),N]iridium(III) dichloromethane disolvate | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Hong, Chang Seop | - |
dc.identifier.doi | 10.1107/S2056989018009970 | - |
dc.identifier.scopusid | 2-s2.0-85051110934 | - |
dc.identifier.wosid | 000440438300016 | - |
dc.identifier.bibliographicCitation | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, v.74, pp.1107 - + | - |
dc.relation.isPartOf | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | - |
dc.citation.title | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | - |
dc.citation.volume | 74 | - |
dc.citation.startPage | 1107 | - |
dc.citation.endPage | + | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Crystallography | - |
dc.relation.journalWebOfScienceCategory | Crystallography | - |
dc.subject.keywordPlus | IRIDIUM(III) COMPLEXES | - |
dc.subject.keywordPlus | PHOSPHORESCENCE | - |
dc.subject.keywordAuthor | crystal structure | - |
dc.subject.keywordAuthor | cyclometalated iridium(III) complex | - |
dc.subject.keywordAuthor | Schiff base ligand | - |
dc.subject.keywordAuthor | C2N3O coordination set | - |
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