Amphiphilic ligand exchange reaction-induced supercapacitor electrodes with high volumetric and scalable areal capacitances
DC Field | Value | Language |
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dc.contributor.author | Nam, Donghyeon | - |
dc.contributor.author | Heo, Yeongbeom | - |
dc.contributor.author | Cheong, Sanghyuk | - |
dc.contributor.author | Ko, Yongmin | - |
dc.contributor.author | Cho, Jinhan | - |
dc.date.accessioned | 2021-09-02T11:34:53Z | - |
dc.date.available | 2021-09-02T11:34:53Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2018-05-15 | - |
dc.identifier.issn | 0169-4332 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/75537 | - |
dc.description.abstract | We introduce high-performance supercapacitor electrodes with ternary components prepared from consecutive amphiphilic ligand-exchange-based layer-by-layer (LbL) assembly among amine-functionalized multi-walled carbon nanotubes (NH2-MWCNTs) in alcohol, oleic acid-stabilized Fe3O4 nanoparticles (OA-Fe3O4 NPs) in toluene, and semiconducting polymers (PEDOT: PSS) in water. The periodic insertion of semiconducting polymers within the (OA-Fe3O4 NP/NH2-MWCNT)(n) multilayer-coated indium tin oxide (ITO) electrode enhanced the volumetric and areal capacitances up to 408 +/- 4 F cm(-3) and 8.79 +/- 0.06 mF cm(-2) at 5 mV s(-1), respectively, allowing excellent cycling stability (98.8% of the initial capacitance after 5000 cycles) and good rate capability. These values were higher than those of the OA-Fe3O4 NP/NH2-MWCNT multilayered electrode without semiconducting polymer linkers (volumetric capacitance similar to 241 +/- 4 F cm(-3) and areal capacitance similar to 1.95 +/- 0.03 mF cm(-2)) at the same scan rate. Furthermore, when the asymmetric supercapacitor cells (ASCs) were prepared using OA-Fe3O4 NP-and OA-MnO NP-based ternary component electrodes, they displayed high volumetric energy (0.36 mW h cm(-3)) and power densities (820 mW cm(-3)). (C) 2018 Elsevier B. V. All rights reserved. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER | - |
dc.subject | FLEXIBLE ASYMMETRIC SUPERCAPACITORS | - |
dc.subject | ELECTROCHEMICAL ENERGY-STORAGE | - |
dc.subject | SOLID-STATE SUPERCAPACITORS | - |
dc.subject | IRON-OXIDE NANOPARTICLES | - |
dc.subject | CORE-SHELL NANOWIRES | - |
dc.subject | HIGH-PERFORMANCE | - |
dc.subject | CONDUCTIVE PAPER | - |
dc.subject | MULTILAYER FILMS | - |
dc.subject | CAPACITORS | - |
dc.subject | SURFACE | - |
dc.title | Amphiphilic ligand exchange reaction-induced supercapacitor electrodes with high volumetric and scalable areal capacitances | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Cho, Jinhan | - |
dc.identifier.doi | 10.1016/j.apsusc.2018.01.153 | - |
dc.identifier.scopusid | 2-s2.0-85041428693 | - |
dc.identifier.wosid | 000427461000086 | - |
dc.identifier.bibliographicCitation | APPLIED SURFACE SCIENCE, v.440, pp.730 - 740 | - |
dc.relation.isPartOf | APPLIED SURFACE SCIENCE | - |
dc.citation.title | APPLIED SURFACE SCIENCE | - |
dc.citation.volume | 440 | - |
dc.citation.startPage | 730 | - |
dc.citation.endPage | 740 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Coatings & Films | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.subject.keywordPlus | FLEXIBLE ASYMMETRIC SUPERCAPACITORS | - |
dc.subject.keywordPlus | ELECTROCHEMICAL ENERGY-STORAGE | - |
dc.subject.keywordPlus | SOLID-STATE SUPERCAPACITORS | - |
dc.subject.keywordPlus | IRON-OXIDE NANOPARTICLES | - |
dc.subject.keywordPlus | CORE-SHELL NANOWIRES | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE | - |
dc.subject.keywordPlus | CONDUCTIVE PAPER | - |
dc.subject.keywordPlus | MULTILAYER FILMS | - |
dc.subject.keywordPlus | CAPACITORS | - |
dc.subject.keywordPlus | SURFACE | - |
dc.subject.keywordAuthor | Supercapacitor | - |
dc.subject.keywordAuthor | Amphiphilic ligand exchange | - |
dc.subject.keywordAuthor | Multi-walled carbon nanotubes | - |
dc.subject.keywordAuthor | Oleic-acid-stabilized iron oxide | - |
dc.subject.keywordAuthor | PEDOT:PSS | - |
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