A Planar Cyclopentadithiophene-Benzothiadiazole-Based Copolymer with sp(2)-Hybridized Bis(alkylsulfanyl)methylene Substituents for Organic Thermoelectric Devices
DC Field | Value | Language |
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dc.contributor.author | Lee, Jiae | - |
dc.contributor.author | Kim, Jaeyun | - |
dc.contributor.author | Thanh Luan Nguyen | - |
dc.contributor.author | Kim, Miso | - |
dc.contributor.author | Park, Juhyung | - |
dc.contributor.author | Lee, Yeran | - |
dc.contributor.author | Hwang, Sungu | - |
dc.contributor.author | Kwon, Young-Wan | - |
dc.contributor.author | Kwak, Jeonghun | - |
dc.contributor.author | Woo, Han Young | - |
dc.date.accessioned | 2021-09-02T11:37:36Z | - |
dc.date.available | 2021-09-02T11:37:36Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2018-05-08 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/75559 | - |
dc.description.abstract | A semicrystalline p-type thermoelectric conjugated polymer based on a polymer backbone of cyclopentadithiophene and benzothiadiazole, poly[(4,4'-(bis-(hexyldecylsulfanyl)methylene)cyclopenta[2,1-b:3,4-b']- dithiophene)-alt-(benzo[c][1,2,5]thiadiazole)] (PCPDTSBT), is designed and synthesized by replacing normal alkyl side-chains with bis(alkylsulfanyl)methylene substituents. The sp(2)-hybridized olefinic bis(alkylsulfanyl)methylene side-chains and the sulfur-sulfur (S-S) chalcogen interactions extend a chain planarity with strong interchain packing, which is confirmed by density functional calculations and morphological studies, i.e., grazing incidence X-ray scattering measurement. The doping, electrical, morphological, and thermoelectric characteristics of PCPDTSBT are investigated by comparison with those of p oly [(4,4'-bis(2-ethylhexyl)cyclopenta[2,1-b:3,4--b']dithiophene)-alt-(benzo[c][1,2,5]thiadiazole)] (PCPDTBT) with ethylhexyl side-chains. Upon doping with a Lewis acid, B(C6F5)(3), the maximum electrical conductivity (7.47 S cm(-1)) of PCPDTSBT is similar to 1 order higher than that (0.65 S cm(-1)) of PCPDTBT, and the best power factor is measured to be 7.73 mu W m(-1) K-2 for PCPDTSBT with doping 9 mol % of B(C6F5)(3). The Seebeck coefficient-electrical conductivity relation is analyzed by using a charge transport model for polymers, suggesting that the doped PCPDTSBT film has superb charge transport property based on a high crystallinity with olefinic side-chains. This study emphasizes the importance of side-chain engineering by using the sp(2)-hybridized olefinic substituents to modulate interchain packing, crystalline morphology, and the resulting electrical properties. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | THIN-FILM TRANSISTORS | - |
dc.subject | CONDUCTING POLYMERS | - |
dc.subject | SOLAR-CELLS | - |
dc.subject | CONJUGATED POLYMERS | - |
dc.subject | CHARGE-TRANSPORT | - |
dc.subject | POWER-FACTOR | - |
dc.subject | SIDE-CHAINS | - |
dc.subject | PEDOTPSS | - |
dc.subject | SEMICONDUCTORS | - |
dc.subject | ENHANCEMENT | - |
dc.title | A Planar Cyclopentadithiophene-Benzothiadiazole-Based Copolymer with sp(2)-Hybridized Bis(alkylsulfanyl)methylene Substituents for Organic Thermoelectric Devices | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kwon, Young-Wan | - |
dc.contributor.affiliatedAuthor | Woo, Han Young | - |
dc.identifier.doi | 10.1021/acs.macromol.8b00419 | - |
dc.identifier.scopusid | 2-s2.0-85046638537 | - |
dc.identifier.wosid | 000432094700014 | - |
dc.identifier.bibliographicCitation | MACROMOLECULES, v.51, no.9, pp.3360 - 3368 | - |
dc.relation.isPartOf | MACROMOLECULES | - |
dc.citation.title | MACROMOLECULES | - |
dc.citation.volume | 51 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 3360 | - |
dc.citation.endPage | 3368 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.subject.keywordPlus | THIN-FILM TRANSISTORS | - |
dc.subject.keywordPlus | CONDUCTING POLYMERS | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | CHARGE-TRANSPORT | - |
dc.subject.keywordPlus | POWER-FACTOR | - |
dc.subject.keywordPlus | SIDE-CHAINS | - |
dc.subject.keywordPlus | PEDOTPSS | - |
dc.subject.keywordPlus | SEMICONDUCTORS | - |
dc.subject.keywordPlus | ENHANCEMENT | - |
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