Tailored Porous ZnCo2O4 Nanofibrous Electrocatalysts for Lithium-Oxygen Batteries
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Jae-Chan | - |
dc.contributor.author | Lee, Gwang-Hee | - |
dc.contributor.author | Lee, Seun | - |
dc.contributor.author | Oh, Seung-Ik | - |
dc.contributor.author | Kang, Yongku | - |
dc.contributor.author | Kim, Dong-Wan | - |
dc.date.accessioned | 2021-09-02T14:53:12Z | - |
dc.date.available | 2021-09-02T14:53:12Z | - |
dc.date.created | 2021-06-16 | - |
dc.date.issued | 2018-02-22 | - |
dc.identifier.issn | 2196-7350 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/77320 | - |
dc.description.abstract | Lithium-oxygen batteries are considered a next-generation technology owing to their extremely high theoretical energy density despite many challenges such as low round-trip efficiency and poor cyclability. The air-cathode structure and pore properties play a key role in solving these problems. In this study, we fabricate ZnCo2O4 nanofibers and design a porous nanostructure using a facile electrospinning process and selective etching of ZnO as the cathode material in lithium-oxygen batteries. First, non-porous ZnCo2O4 nanofiber electrodes accomplish high catalytic activity and good cycling stability during 116 cycles with a limited capacity of 1000 mA h g(-1) at a current density of 500 mA g(-1). For enhanced catalytic activity and cyclability, ZnO included ZnCo2O4 nanofibers are prepared using a Zn-excess electrospun solution and porous ZnCo2O4 nanofibers are fabricated via selective etching of ZnO. Porous ZnCo2O4 nanofiber electrodes exhibit excellent electrocatalytic activity and cyclability for 226 cycles with a limited capacity of 1000 mA h g(-1) at a current density of 500 mA g(-1). The exceptional catalytic properties explain the synergistic effect of the one-dimensional nanostructure and porous structure with an appropriate pore diameter, providing a large active site and an efficient electron pathway during the Li2O2 formation/decomposition process. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY | - |
dc.subject | EFFICIENT BIFUNCTIONAL CATALYST | - |
dc.subject | LI-O-2 BATTERIES | - |
dc.subject | MESOPOROUS ZNCO2O4 | - |
dc.subject | ELECTRODE MATERIAL | - |
dc.subject | METAL-OXIDE | - |
dc.subject | MICROSPHERES | - |
dc.subject | NANOTUBES | - |
dc.subject | GRAPHENE | - |
dc.subject | NANORODS | - |
dc.subject | FACILE | - |
dc.title | Tailored Porous ZnCo2O4 Nanofibrous Electrocatalysts for Lithium-Oxygen Batteries | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lee, Gwang-Hee | - |
dc.contributor.affiliatedAuthor | Kim, Dong-Wan | - |
dc.identifier.doi | 10.1002/admi.201701234 | - |
dc.identifier.scopusid | 2-s2.0-85037732780 | - |
dc.identifier.wosid | 000425729300012 | - |
dc.identifier.bibliographicCitation | ADVANCED MATERIALS INTERFACES, v.5, no.4 | - |
dc.relation.isPartOf | ADVANCED MATERIALS INTERFACES | - |
dc.citation.title | ADVANCED MATERIALS INTERFACES | - |
dc.citation.volume | 5 | - |
dc.citation.number | 4 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.subject.keywordPlus | EFFICIENT BIFUNCTIONAL CATALYST | - |
dc.subject.keywordPlus | LI-O-2 BATTERIES | - |
dc.subject.keywordPlus | MESOPOROUS ZNCO2O4 | - |
dc.subject.keywordPlus | ELECTRODE MATERIAL | - |
dc.subject.keywordPlus | METAL-OXIDE | - |
dc.subject.keywordPlus | MICROSPHERES | - |
dc.subject.keywordPlus | NANOTUBES | - |
dc.subject.keywordPlus | GRAPHENE | - |
dc.subject.keywordPlus | NANORODS | - |
dc.subject.keywordPlus | FACILE | - |
dc.subject.keywordAuthor | electrospinning | - |
dc.subject.keywordAuthor | lithium-oxygen batteries | - |
dc.subject.keywordAuthor | nanofibers | - |
dc.subject.keywordAuthor | porous structure | - |
dc.subject.keywordAuthor | ZnCo2O4 | - |
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