Electrochemical CO2 Reduction at Glassy Carbon Electrodes Functionalized by Mn-I and Re-I Organometallic Complexes
DC Field | Value | Language |
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dc.contributor.author | Sun, Cunfa | - |
dc.contributor.author | Rotundo, Laura | - |
dc.contributor.author | Garino, Claudio | - |
dc.contributor.author | Nencini, Luca | - |
dc.contributor.author | Yoon, Sam S. | - |
dc.contributor.author | Gobetto, Roberto | - |
dc.contributor.author | Nervi, Carlo | - |
dc.date.accessioned | 2021-09-02T23:01:18Z | - |
dc.date.available | 2021-09-02T23:01:18Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2017-11-17 | - |
dc.identifier.issn | 1439-4235 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/81527 | - |
dc.description.abstract | The catalytic activities towards electrochemical CO2 reduction of two new rhenium and manganese complexes, namely fac-Mn(apbpy)(CO)(3)Br (1) and fac-Re(apbpy)(CO)(3)Cl (2) (apbpy= 4-(4-aminophenyl)-2,2'-bipyridine), in both homogeneous and heterogeneous phases are compared. A glassy carbon electrode (GCE) surface has been functionalized with complexes 1 and 2 by two approaches: a) direct electrochemical oxidation of the amino group with formation of C-N bonds, and b) electrochemical reduction of the corresponding diazonium salts with formation of C-C bonds. The chemically modified GCEs show efficient conversion of CO2 into CO, with turnover numbers (TONs) about 60 times higher than those of the corresponding catalysts in homogeneous solutions, and in a much shorter time. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | LOCAL PROTON SOURCE | - |
dc.subject | ELECTROCATALYTIC REDUCTION | - |
dc.subject | RHENIUM(I) COMPLEXES | - |
dc.subject | RUTHENIUM COMPLEXES | - |
dc.subject | MANGANESE | - |
dc.subject | DIOXIDE | - |
dc.subject | BIPYRIDINE | - |
dc.subject | CATALYSTS | - |
dc.subject | SURFACES | - |
dc.subject | LIGANDS | - |
dc.title | Electrochemical CO2 Reduction at Glassy Carbon Electrodes Functionalized by Mn-I and Re-I Organometallic Complexes | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Yoon, Sam S. | - |
dc.identifier.doi | 10.1002/cphc.201700739 | - |
dc.identifier.scopusid | 2-s2.0-85034098059 | - |
dc.identifier.wosid | 000417303900014 | - |
dc.identifier.bibliographicCitation | CHEMPHYSCHEM, v.18, no.22, pp.3219 - 3229 | - |
dc.relation.isPartOf | CHEMPHYSCHEM | - |
dc.citation.title | CHEMPHYSCHEM | - |
dc.citation.volume | 18 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 3219 | - |
dc.citation.endPage | 3229 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Physics | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Physics, Atomic, Molecular & Chemical | - |
dc.subject.keywordPlus | LOCAL PROTON SOURCE | - |
dc.subject.keywordPlus | ELECTROCATALYTIC REDUCTION | - |
dc.subject.keywordPlus | RHENIUM(I) COMPLEXES | - |
dc.subject.keywordPlus | RUTHENIUM COMPLEXES | - |
dc.subject.keywordPlus | MANGANESE | - |
dc.subject.keywordPlus | DIOXIDE | - |
dc.subject.keywordPlus | BIPYRIDINE | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | SURFACES | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordAuthor | carbon dioxide | - |
dc.subject.keywordAuthor | electrode functionalization | - |
dc.subject.keywordAuthor | Mn complexes | - |
dc.subject.keywordAuthor | Re complexes | - |
dc.subject.keywordAuthor | reduction | - |
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