Preparation of Building Blocks for Iterative Suzuki-Miyaura Reactions via Direct Bromination of Aryl Boronic Acids: One-Pot Total Syntheses of Dictyoterphenyls A and B
DC Field | Value | Language |
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dc.contributor.author | Lee, Chun-Young | - |
dc.contributor.author | Cheon, Cheol-Hong | - |
dc.date.accessioned | 2021-09-02T23:05:33Z | - |
dc.date.available | 2021-09-02T23:05:33Z | - |
dc.date.created | 2021-06-18 | - |
dc.date.issued | 2017-11-10 | - |
dc.identifier.issn | 1615-4150 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/81561 | - |
dc.description.abstract | A highly efficient method for the preparation of 4-alkoxy-3-bromophenyl boronic acid N-methyliminodiacetic acid (MIDA) esters as building blocks in iterative Suzuki-Miyaura reactions from the 4-alkoxyphenylboronic acids is described using a boronic acid moiety as a blocking group in bromination reactions. With these MIDA boronates, the total syntheses of dictyoterphenyls A and B were developed in only two separate one-pot operations. Furthermore, we have developed a more practical protocol for the preparation of meta-terphenyl natural products by simply adding the second aryl halide and water to the reaction mixture via the controlled release technique. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | SMALL-MOLECULE SYNTHESIS | - |
dc.subject | STRATEGY | - |
dc.subject | FUNCTIONALIZATION | - |
dc.subject | OLIGOARENES | - |
dc.title | Preparation of Building Blocks for Iterative Suzuki-Miyaura Reactions via Direct Bromination of Aryl Boronic Acids: One-Pot Total Syntheses of Dictyoterphenyls A and B | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Cheon, Cheol-Hong | - |
dc.identifier.doi | 10.1002/adsc.201700733 | - |
dc.identifier.scopusid | 2-s2.0-85030032784 | - |
dc.identifier.wosid | 000416935100017 | - |
dc.identifier.bibliographicCitation | ADVANCED SYNTHESIS & CATALYSIS, v.359, no.21, pp.3831 - 3836 | - |
dc.relation.isPartOf | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.citation.title | ADVANCED SYNTHESIS & CATALYSIS | - |
dc.citation.volume | 359 | - |
dc.citation.number | 21 | - |
dc.citation.startPage | 3831 | - |
dc.citation.endPage | 3836 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.subject.keywordPlus | SMALL-MOLECULE SYNTHESIS | - |
dc.subject.keywordPlus | STRATEGY | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | OLIGOARENES | - |
dc.subject.keywordAuthor | Blocking Group | - |
dc.subject.keywordAuthor | Dictyoterphenyls A and B | - |
dc.subject.keywordAuthor | Iterative Suzuki-Miyaura reaction | - |
dc.subject.keywordAuthor | MIDA Boronates | - |
dc.subject.keywordAuthor | Pot-economy | - |
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