Basic anion-exchange resin (AER)-supported Au-Pd alloy nanoparticles for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA)
DC Field | Value | Language |
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dc.contributor.author | Antonyraj, Churchil A. | - |
dc.contributor.author | Nhan Thanh Thien Huynh | - |
dc.contributor.author | Park, Seok-Kyu | - |
dc.contributor.author | Shin, Seunghan | - |
dc.contributor.author | Kim, Yong Jin | - |
dc.contributor.author | Kim, Sangyong | - |
dc.contributor.author | Lee, Kwan-Young | - |
dc.contributor.author | Cho, Jin Ku | - |
dc.date.accessioned | 2021-09-03T00:02:21Z | - |
dc.date.available | 2021-09-03T00:02:21Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2017-10-25 | - |
dc.identifier.issn | 0926-860X | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/81864 | - |
dc.description.abstract | Au-Pd alloy nanoparticles supported on basic anion-exchange resin (AER) have exceptional catalytic activity for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA) with an equimolar amount of base. SEM-EDX and TEM analyses show that 5-20 nm Au-Pd alloy nanoparticles are well dispersed both on the resin surface and inside resin spheres by a simple procedure without any assistance of additives. XPS analysis reveals that Au- and Pd metals exist in an alloy form on the AER support, which is confirmed by a comparison study with a mixture of AER-supported monometallic nanoparticles (AER-supported Au and AER-supported Pd). In the presence of a 1:1 ratio of Au-Pd alloy nanoparticles over Amberlite IRA-743 resin with O-2 (10 bar) at 373 K in an equimolar Na2CO3 aqueous solution, HMF is oxidized to FDCA with a 93.2% yield. On the other hand, mixture of AER-supported Au and AER-supported Pd affords only a 52% FDCA yield under identical conditions. This catalyst can be used 6 times without any significant loss of activity. FDCA is also obtained from HMF with an 82.9% yield in air (40 bar). | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.subject | 2,5-FURANDICARBOXYLIC ACID | - |
dc.subject | SELECTIVE OXIDATION | - |
dc.subject | AEROBIC OXIDATION | - |
dc.subject | CATALYSTS | - |
dc.subject | ALCOHOLS | - |
dc.subject | DERIVATIVES | - |
dc.subject | MECHANISM | - |
dc.subject | BIOMASS | - |
dc.subject | PHASE | - |
dc.subject | WATER | - |
dc.title | Basic anion-exchange resin (AER)-supported Au-Pd alloy nanoparticles for the oxidation of 5-hydroxymethyl-2-furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA) | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Lee, Kwan-Young | - |
dc.identifier.doi | 10.1016/j.apcata.2017.09.012 | - |
dc.identifier.scopusid | 2-s2.0-85029287581 | - |
dc.identifier.wosid | 000413607100026 | - |
dc.identifier.bibliographicCitation | APPLIED CATALYSIS A-GENERAL, v.547, pp.230 - 236 | - |
dc.relation.isPartOf | APPLIED CATALYSIS A-GENERAL | - |
dc.citation.title | APPLIED CATALYSIS A-GENERAL | - |
dc.citation.volume | 547 | - |
dc.citation.startPage | 230 | - |
dc.citation.endPage | 236 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Environmental Sciences & Ecology | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Environmental Sciences | - |
dc.subject.keywordPlus | 2,5-FURANDICARBOXYLIC ACID | - |
dc.subject.keywordPlus | SELECTIVE OXIDATION | - |
dc.subject.keywordPlus | AEROBIC OXIDATION | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | ALCOHOLS | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | MECHANISM | - |
dc.subject.keywordPlus | BIOMASS | - |
dc.subject.keywordPlus | PHASE | - |
dc.subject.keywordPlus | WATER | - |
dc.subject.keywordAuthor | Anion-exchange resin (AER) | - |
dc.subject.keywordAuthor | Au-Pd alloynanoparticles | - |
dc.subject.keywordAuthor | Oxidation | - |
dc.subject.keywordAuthor | 5-Hydroxymethyl-2-furfural (HMF) | - |
dc.subject.keywordAuthor | 2,5-Furan dicarboxylic acid (FDCA) | - |
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