Scalable ambient synthesis of water-soluble poly(-hydroxythio-ether)s
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hwang, JiHyeon | - |
dc.contributor.author | Choe, Youngson | - |
dc.contributor.author | Bang, Joona | - |
dc.contributor.author | Khan, Anzar | - |
dc.date.accessioned | 2021-09-03T00:09:54Z | - |
dc.date.available | 2021-09-03T00:09:54Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2017-10-15 | - |
dc.identifier.issn | 0887-624X | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/81906 | - |
dc.description.abstract | Proton transfer polymerization through thiol-epoxy click reaction between commercially available and hydrophilic di-thiol and di-epoxide monomers is carried out under ambient conditions to furnish water-soluble polymers. The hydrophilicity of monomers permitted use of aqueous tetrahydrofuran as the reaction medium. A high polarity of this solvent system in turn allowed for using a mild catalyst such as triethylamine for a successful polymerization process. The overall simplicity of the system translated into a simple mixing of monomers and isolation of the reactive polymers in an effortless manner and on any scale required. The structure of the resulting polymers and the extent of di-sulfide defects are studied with the help of 13C- and H-1-NMR spectroscopy. Finally, reactivity of the synthesized polymers is examined through post-polymerization modification reaction at the backbone sulfur atoms through oxidation reaction. The practicality, modularity, further functionalizability, and water solubility aspects of the described family of new poly(-hydroxythio-ether)s is anticipated to accelerate investigations into their potential utility in bio-relevant applications. (c) 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 3381-3386 | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY | - |
dc.subject | PROTON-TRANSFER POLYMERIZATION | - |
dc.subject | EPOXY CLICK CHEMISTRY | - |
dc.subject | AGGREGATION-INDUCED EMISSION | - |
dc.subject | THIOL-ENE CHEMISTRY | - |
dc.subject | MULTIFUNCTIONAL POLYMERS | - |
dc.subject | HYPERBRANCHED POLYMERS | - |
dc.subject | POST-FUNCTIONALIZATION | - |
dc.subject | FACILE SYNTHESIS | - |
dc.subject | METAL-FREE | - |
dc.subject | COPOLYMERS | - |
dc.title | Scalable ambient synthesis of water-soluble poly(-hydroxythio-ether)s | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Bang, Joona | - |
dc.contributor.affiliatedAuthor | Khan, Anzar | - |
dc.identifier.doi | 10.1002/pola.28714 | - |
dc.identifier.scopusid | 2-s2.0-85028706611 | - |
dc.identifier.wosid | 000408938600006 | - |
dc.identifier.bibliographicCitation | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.55, no.20, pp.3381 - 3386 | - |
dc.relation.isPartOf | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.citation.title | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.citation.volume | 55 | - |
dc.citation.number | 20 | - |
dc.citation.startPage | 3381 | - |
dc.citation.endPage | 3386 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.subject.keywordPlus | PROTON-TRANSFER POLYMERIZATION | - |
dc.subject.keywordPlus | EPOXY CLICK CHEMISTRY | - |
dc.subject.keywordPlus | AGGREGATION-INDUCED EMISSION | - |
dc.subject.keywordPlus | THIOL-ENE CHEMISTRY | - |
dc.subject.keywordPlus | MULTIFUNCTIONAL POLYMERS | - |
dc.subject.keywordPlus | HYPERBRANCHED POLYMERS | - |
dc.subject.keywordPlus | POST-FUNCTIONALIZATION | - |
dc.subject.keywordPlus | FACILE SYNTHESIS | - |
dc.subject.keywordPlus | METAL-FREE | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordAuthor | click polymerization | - |
dc.subject.keywordAuthor | functionalization of polymers | - |
dc.subject.keywordAuthor | step-growth polymerization | - |
dc.subject.keywordAuthor | thiol-epoxy reaction | - |
dc.subject.keywordAuthor | water-soluble polymers | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.