Synthesis of Flower-like Cu-3[MoO4](2)O from Cu-3(MoO4)(2)(OH)(2) and Its Application for Lithium-Ion Batteries: Structure-Electrochemical Property Relationships
DC Field | Value | Language |
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dc.contributor.author | Swain, Basudev | - |
dc.contributor.author | Lee, Duk-Hee | - |
dc.contributor.author | Kim, Jun-Sik | - |
dc.contributor.author | Lee, Chan-Gi | - |
dc.contributor.author | Kim, Dong-Wan | - |
dc.contributor.author | Park, Kyung-Soo | - |
dc.date.accessioned | 2021-09-03T00:44:52Z | - |
dc.date.available | 2021-09-03T00:44:52Z | - |
dc.date.created | 2021-06-19 | - |
dc.date.issued | 2017-10 | - |
dc.identifier.issn | 2196-0216 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/82026 | - |
dc.description.abstract | Flower-like Cu-3[MoO4](2)O microspheres have been synthesized by using a sequential process from lindgrenite (Cu-3(MoO4)(2)(OH)(2)). Lindgrenite nanoflowers were synthesized through a simpler route by using an aqueous chemical precipitation technique at room temperature without any surfactants or template. Subsequently, 3D flower-like Cu-3[MoO4](2)O microspheres have been synthesized by annealing at 300 degrees C for 2h from lindgrenite (Cu-3(MoO4)(2)(OH)(2)). From the XRD pattern, FTIR spectrum, SEM and TEM analysis, flower-like Cu-3[MoO4](2)O (ca. 5m) microspheres have been obtained, which were assembled from 3-4nm thick nanosheets with an orthorhombic structure. Application of 3D flower-like microspheres as an anode material for lithium-ion batteries (LIBs) has been investigated and the possible electrochemical mechanism is analyzed. Electrochemical characterization of the Cu-3[MoO4](2)O nanoflowers as an anode material for LIBs has exhibited good cycle stability and a high coulombic efficiency during operation. The electrochemical activity was attributed to the unique structure of the Cu-3[MoO4](2)O microspheres, which provide more active sites for Li-ion storage as well as a reduced transfer resistance. This work has explored a simple synthesis strategy for the synthesis of flower-like Cu-3[MoO4](2)O microspheres without templates, additives, or surfactants, which exhibit a basis for not only high electrochemical performance in reversible Li storage, but also cycle stability. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | ANODE MATERIALS | - |
dc.subject | NANOWIRE ARRAYS | - |
dc.subject | COBALT OXIDE | - |
dc.subject | PERFORMANCE | - |
dc.subject | CU3MO2O9 | - |
dc.subject | STORAGE | - |
dc.subject | NANOMATERIALS | - |
dc.subject | POLYOXOMETALATE | - |
dc.subject | NANOSTRUCTURES | - |
dc.subject | NANOPARTICLES | - |
dc.title | Synthesis of Flower-like Cu-3[MoO4](2)O from Cu-3(MoO4)(2)(OH)(2) and Its Application for Lithium-Ion Batteries: Structure-Electrochemical Property Relationships | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Kim, Dong-Wan | - |
dc.identifier.doi | 10.1002/celc.201700499 | - |
dc.identifier.scopusid | 2-s2.0-85023202163 | - |
dc.identifier.wosid | 000412892600027 | - |
dc.identifier.bibliographicCitation | CHEMELECTROCHEM, v.4, no.10, pp.2608 - 2617 | - |
dc.relation.isPartOf | CHEMELECTROCHEM | - |
dc.citation.title | CHEMELECTROCHEM | - |
dc.citation.volume | 4 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 2608 | - |
dc.citation.endPage | 2617 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Electrochemistry | - |
dc.relation.journalWebOfScienceCategory | Electrochemistry | - |
dc.subject.keywordPlus | ANODE MATERIALS | - |
dc.subject.keywordPlus | NANOWIRE ARRAYS | - |
dc.subject.keywordPlus | COBALT OXIDE | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | CU3MO2O9 | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | NANOMATERIALS | - |
dc.subject.keywordPlus | POLYOXOMETALATE | - |
dc.subject.keywordPlus | NANOSTRUCTURES | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordAuthor | Cu-3[MoO4](2)O | - |
dc.subject.keywordAuthor | flower-like microspheres | - |
dc.subject.keywordAuthor | 3D nanostructures | - |
dc.subject.keywordAuthor | anode materials | - |
dc.subject.keywordAuthor | Li-ion batteries | - |
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