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Concise catalytic asymmetric total syntheses of ancistrocladinium A and its atropdiastereomer
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| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Kim, Kyung-Hee | - |
| dc.contributor.author | Cheon, Cheol-Hong | - |
| dc.date.accessioned | 2021-09-03T04:09:11Z | - |
| dc.date.available | 2021-09-03T04:09:11Z | - |
| dc.date.created | 2021-06-16 | - |
| dc.date.issued | 2017-07-01 | - |
| dc.identifier.issn | 2052-4110 | - |
| dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/82871 | - |
| dc.description.abstract | Asymmetric total syntheses of ancistrocladinium A and its atropdiastereomer, in an atropisomerically pure form, are described. Chiral phosphoric acid-catalyzed asymmetric reductive amination of 1-aryl propanone and naphthylamine followed by acetylation provided two atropisomerically pure tertiary amides. Subsequent stereospecific Bischler-Napieralski reaction of each of these tertiary amides with triflic anhydride provided ancistrocladinium A or its atropdiastereomer, as a single atropisomer, respectively. | - |
| dc.language | English | - |
| dc.language.iso | en | - |
| dc.publisher | ROYAL SOC CHEMISTRY | - |
| dc.subject | STRONGER BRONSTED ACIDS | - |
| dc.subject | TRANSFER HYDROGENATION | - |
| dc.subject | REDUCTIVE AMINATION | - |
| dc.subject | PHOSPHORIC-ACID | - |
| dc.subject | IMINES | - |
| dc.title | Concise catalytic asymmetric total syntheses of ancistrocladinium A and its atropdiastereomer | - |
| dc.type | Article | - |
| dc.contributor.affiliatedAuthor | Cheon, Cheol-Hong | - |
| dc.identifier.doi | 10.1039/c7qo00195a | - |
| dc.identifier.scopusid | 2-s2.0-85021768109 | - |
| dc.identifier.wosid | 000405863700022 | - |
| dc.identifier.bibliographicCitation | ORGANIC CHEMISTRY FRONTIERS, v.4, no.7, pp.1341 - 1349 | - |
| dc.relation.isPartOf | ORGANIC CHEMISTRY FRONTIERS | - |
| dc.citation.title | ORGANIC CHEMISTRY FRONTIERS | - |
| dc.citation.volume | 4 | - |
| dc.citation.number | 7 | - |
| dc.citation.startPage | 1341 | - |
| dc.citation.endPage | 1349 | - |
| dc.type.rims | ART | - |
| dc.type.docType | Article | - |
| dc.description.journalClass | 1 | - |
| dc.description.journalRegisteredClass | scie | - |
| dc.description.journalRegisteredClass | scopus | - |
| dc.relation.journalResearchArea | Chemistry | - |
| dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
| dc.subject.keywordPlus | STRONGER BRONSTED ACIDS | - |
| dc.subject.keywordPlus | TRANSFER HYDROGENATION | - |
| dc.subject.keywordPlus | REDUCTIVE AMINATION | - |
| dc.subject.keywordPlus | PHOSPHORIC-ACID | - |
| dc.subject.keywordPlus | IMINES | - |
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