Ethanol-Processable, Highly Crystalline Conjugated Polymers for Eco-Friendly Fabrication of Organic Transistors and Solar Cells
DC Field | Value | Language |
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dc.contributor.author | Thanh Luan Nguyen | - |
dc.contributor.author | Leep, Changyeon | - |
dc.contributor.author | Kirn, Hyoeun | - |
dc.contributor.author | Kim, Youngwoong | - |
dc.contributor.author | Lee, Wonho | - |
dc.contributor.author | Oh, Joon Hal | - |
dc.contributor.author | Kim, Bumjoon J. | - |
dc.contributor.author | Woo, Han Young | - |
dc.date.accessioned | 2021-09-03T05:02:14Z | - |
dc.date.available | 2021-09-03T05:02:14Z | - |
dc.date.created | 2021-06-16 | - |
dc.date.issued | 2017-06-13 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/83139 | - |
dc.description.abstract | We report eco- and human-friendly fabrication of organic field-effect transistors (OFETs) and polymer solar cells (PSCs) using only ethanol as a processing solvent at ambient condition, in stark contrast to that involving the use of halogenated and/or aromatic solvents. New ethanol-processable electroactive materials, p-type polymer (PPDT2FBT-A) and n-type bis-adduct fullerene acceptor (Bis-C-60-A) are designed rationally by incorporation of oligoethylene glycol (OEG) side-chains. By ethanol processing, PPDT2FBT-A shows a broad light absorption in the range of 300-700 nm and highly crystalline interchain ordering with out-of-plane interlamellar scattering up to (400) with strong pi-pi stacking. As a result, the ethanol-processed PPDT2FBT-A OFETs yield high charge-carrier mobilities up to 1.0 x 10(-2) cm(2) s(-1), which is the highest value reported to date from alcohol-processed devices. Importantly, the ethanol-processed PPDT2FBT-A OFET outperformed that processed using typical processing solvent, chlorobenzene (CB), with similar to 10-fold enhancement in hole mobility, because the highly edge-on oriented packing of PPDT2FBT-A was produced by ethanol-process. Also, for the first time, significant photovoltaic performance was achieved for the ethanol-processed device of PPDT2FBT-A and Bis-C-60-A due to the formation of an interpenetrating nanofibrillar morphology of highly crystalline PPDT2FBT-A polymers. The relationships between molecular structure, nanoscale morphology and electronic properties within ethanol-processed OFETs and PSCs were elucidated by comparing to typical CB-processed devices. These comparisons provide important guidelines for the design of new ethanol/water-soluble active layer materials and their use in the development of green solvent-processed efficient OFETs and PSCs. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | OPEN-CIRCUIT VOLTAGE | - |
dc.subject | FIELD-EFFECT TRANSISTORS | - |
dc.subject | CHARGE-CARRIER-MOBILITY | - |
dc.subject | HIGH-PERFORMANCE | - |
dc.subject | PHOTOVOLTAIC PERFORMANCE | - |
dc.subject | SEMICONDUCTING POLYMERS | - |
dc.subject | MOLECULAR-ORIENTATION | - |
dc.subject | BANDGAP POLYMER | - |
dc.subject | CURRENT-DENSITY | - |
dc.subject | EFFICIENCY | - |
dc.title | Ethanol-Processable, Highly Crystalline Conjugated Polymers for Eco-Friendly Fabrication of Organic Transistors and Solar Cells | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Woo, Han Young | - |
dc.identifier.doi | 10.1021/acs.macromol.7b00452 | - |
dc.identifier.scopusid | 2-s2.0-85020696216 | - |
dc.identifier.wosid | 000403530400033 | - |
dc.identifier.bibliographicCitation | MACROMOLECULES, v.50, no.11, pp.4415 - 4424 | - |
dc.relation.isPartOf | MACROMOLECULES | - |
dc.citation.title | MACROMOLECULES | - |
dc.citation.volume | 50 | - |
dc.citation.number | 11 | - |
dc.citation.startPage | 4415 | - |
dc.citation.endPage | 4424 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.subject.keywordPlus | OPEN-CIRCUIT VOLTAGE | - |
dc.subject.keywordPlus | FIELD-EFFECT TRANSISTORS | - |
dc.subject.keywordPlus | CHARGE-CARRIER-MOBILITY | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE | - |
dc.subject.keywordPlus | PHOTOVOLTAIC PERFORMANCE | - |
dc.subject.keywordPlus | SEMICONDUCTING POLYMERS | - |
dc.subject.keywordPlus | MOLECULAR-ORIENTATION | - |
dc.subject.keywordPlus | BANDGAP POLYMER | - |
dc.subject.keywordPlus | CURRENT-DENSITY | - |
dc.subject.keywordPlus | EFFICIENCY | - |
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