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Electrochemical properties of P2-type Na2/3Ni1/3Mn2/3O2 plates synthesized by spray pyrolysis process for sodium-ion batteries

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dc.contributor.authorLee, Seung Yeon-
dc.contributor.authorKim, Jong Hwa-
dc.contributor.authorKang, Yun Chan-
dc.date.accessioned2021-09-03T10:49:18Z-
dc.date.available2021-09-03T10:49:18Z-
dc.date.created2021-06-16-
dc.date.issued2017-01-20-
dc.identifier.issn0013-4686-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/84891-
dc.description.abstractP2-type Na2/3Ni1/3Mn2/3O2 plates with homogeneous composition and regular morphology are prepared by spray pyrolysis. The rhombohedral P3-Na2/3Ni1/3Mn2/3O2 microspheres formed by one-pot spray pyrolysis transform into hexagonal P-2-Na2/3Ni1/3Mn2/3O2 plates after post-treatment at temperatures between 800 and 1000 degrees C. The mean size and thickness of P-2-Na2/3Ni1/3Mn2/3O2 plates obtained after post-treatment at 900 degrees C are 2.2 mm and 550 nm, respectively. The initial discharge capacities of 'P-2-Na(2/3)Ni(1/3)Mn(2/3)O(2)plates formed at 800, 900, and 1000 degrees C at a current rate of 0.1C are 69, 86, and 80 mA h g(1), respectively, while the discharge capacities after 200 cycles are 68, 80, and 76 mA h g(1), respectively. However, the discharge capacities of P3-Na2/3Ni1/3Mn2/3O2 powders decrease from 62 to 50 mA h g(1) after 200 cycles. P-2-Na2/3Ni1/3Mn2/3O2 plates show low charge-transfer resistance and also exhibit better rate performance than P3-Na2/3Ni1/3Mn2/3O2 powders. (C) 2016 Elsevier Ltd. All rights reserved.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectTRANSITION-METAL OXIDES-
dc.subjectCATHODE MATERIAL-
dc.subjectSUPERIOR CATHODE-
dc.subjectHIGH-CAPACITY-
dc.subjectPERFORMANCE-
dc.subjectELECTRODE-
dc.subjectPOWDERS-
dc.subjectPARTICLES-
dc.subjectCARBON-
dc.titleElectrochemical properties of P2-type Na2/3Ni1/3Mn2/3O2 plates synthesized by spray pyrolysis process for sodium-ion batteries-
dc.typeArticle-
dc.contributor.affiliatedAuthorKang, Yun Chan-
dc.identifier.doi10.1016/j.electacta.2016.11.141-
dc.identifier.scopusid2-s2.0-85007087216-
dc.identifier.wosid000393502500009-
dc.identifier.bibliographicCitationELECTROCHIMICA ACTA, v.225, pp.86 - 92-
dc.relation.isPartOfELECTROCHIMICA ACTA-
dc.citation.titleELECTROCHIMICA ACTA-
dc.citation.volume225-
dc.citation.startPage86-
dc.citation.endPage92-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaElectrochemistry-
dc.relation.journalWebOfScienceCategoryElectrochemistry-
dc.subject.keywordPlusTRANSITION-METAL OXIDES-
dc.subject.keywordPlusCATHODE MATERIAL-
dc.subject.keywordPlusSUPERIOR CATHODE-
dc.subject.keywordPlusHIGH-CAPACITY-
dc.subject.keywordPlusPERFORMANCE-
dc.subject.keywordPlusELECTRODE-
dc.subject.keywordPlusPOWDERS-
dc.subject.keywordPlusPARTICLES-
dc.subject.keywordPlusCARBON-
dc.subject.keywordAuthorEnergy storage materials-
dc.subject.keywordAuthorSodium-ion batteries-
dc.subject.keywordAuthorCathode material-
dc.subject.keywordAuthorSpray pyrolysis-
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