Thermally reversible self-healing polysilsesquioxane structure-property relationships based on Diels-Alder chemistry
- Authors
- Jo, Young Yeol; Lee, Albert S.; Baek, Kyung-Youl; Lee, Heon; Hwang, Seung Sang
- Issue Date
- 13-1월-2017
- Publisher
- ELSEVIER SCI LTD
- Keywords
- Silsesquioxane; Self-healing polymers; Diels-Alder chemistry
- Citation
- POLYMER, v.108, pp.58 - 65
- Indexed
- SCIE
SCOPUS
- Journal Title
- POLYMER
- Volume
- 108
- Start Page
- 58
- End Page
- 65
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/84919
- DOI
- 10.1016/j.polymer.2016.11.040
- ISSN
- 0032-3861
- Abstract
- An in-depth examination of the self-healing properties of both dienophile and diene functionalized ladder-like structured polysilsesquioxane copolymers and terpolymers was investigated. Through functionalization of both diene and dienophile on the double-stranded siloxane backbone with ternary n-alkyl functional groups acting as chain mobility control, the effect of chain mobility and chemical structure on self-healing and mechanical properties were elucidated. All of the single component self healing hybrid materials exhibited fast healing times (similar to 5 min), and their de-crosslinked adducts exhibited exceptional retention of solubility in common organic solvents for good reusability, all while having inherent high thermal stability and optical transparency. (C) 2016 Elsevier Ltd. All rights reserved.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - College of Engineering > Department of Materials Science and Engineering > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.