Addressing the mid-point of polymer chains for multiple functionalization purposes through sequential thiol-epoxy 'click' and esterification reactions
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gadwal, Ikhlas | - |
dc.contributor.author | Eom, Taejun | - |
dc.contributor.author | Hwang, JiHyeon | - |
dc.contributor.author | Choe, Youngson | - |
dc.contributor.author | Bang, Joona | - |
dc.contributor.author | Khan, Anzar | - |
dc.date.accessioned | 2021-09-03T15:16:00Z | - |
dc.date.available | 2021-09-03T15:16:00Z | - |
dc.date.created | 2021-06-16 | - |
dc.date.issued | 2017 | - |
dc.identifier.issn | 2046-2069 | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/86404 | - |
dc.description.abstract | A synthetic strategy is devised for the preparation of mid-chain multifunctional polymers. In this strategy, small molecules carrying one or two epoxide units along with two polymerization-initiating sites were prepared in two to three synthetic steps. Atom transfer radical polymerization (ATRP) of methylmethacrylate (MMA) monomer using the newly designed initiators gave rise to epoxide-mid-reactive polymers. A careful chain cleavage study confirmed the midpoint location of the reactive site(s) on the polymer chain. Dual-modification of these reactive epoxide unit(s) through sequential thiol-epoxy and esterification reactions then afforded the midpoint multiply functionalized polymeric structures. Due to compatibility of the ATRP process with the reactive epoxide unit(s) and the cascade nature of the functionalization processes, the present strategy is free from the protective-group requirement of organic synthesis. Moreover, it allows for varying the number and nature of functionalities at the midpoint of a polymer chain. | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | TRANSFER RADICAL POLYMERIZATION | - |
dc.subject | STEP-GROWTH POLYMERIZATION | - |
dc.subject | MIKTOARM STAR TERPOLYMERS | - |
dc.subject | MULTIFUNCTIONAL POLYMERS | - |
dc.subject | GLYCIDYL METHACRYLATE | - |
dc.subject | RAFT POLYMERIZATION | - |
dc.subject | SURFACE-PROPERTIES | - |
dc.subject | GRAFT-COPOLYMERS | - |
dc.subject | ONE-POT | - |
dc.subject | CHEMISTRY | - |
dc.title | Addressing the mid-point of polymer chains for multiple functionalization purposes through sequential thiol-epoxy 'click' and esterification reactions | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Bang, Joona | - |
dc.contributor.affiliatedAuthor | Khan, Anzar | - |
dc.identifier.doi | 10.1039/c7ra02702h | - |
dc.identifier.scopusid | 2-s2.0-85017139395 | - |
dc.identifier.wosid | 000399242100004 | - |
dc.identifier.bibliographicCitation | RSC ADVANCES, v.7, no.32, pp.19439 - 19447 | - |
dc.relation.isPartOf | RSC ADVANCES | - |
dc.citation.title | RSC ADVANCES | - |
dc.citation.volume | 7 | - |
dc.citation.number | 32 | - |
dc.citation.startPage | 19439 | - |
dc.citation.endPage | 19447 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.subject.keywordPlus | TRANSFER RADICAL POLYMERIZATION | - |
dc.subject.keywordPlus | STEP-GROWTH POLYMERIZATION | - |
dc.subject.keywordPlus | MIKTOARM STAR TERPOLYMERS | - |
dc.subject.keywordPlus | MULTIFUNCTIONAL POLYMERS | - |
dc.subject.keywordPlus | GLYCIDYL METHACRYLATE | - |
dc.subject.keywordPlus | RAFT POLYMERIZATION | - |
dc.subject.keywordPlus | SURFACE-PROPERTIES | - |
dc.subject.keywordPlus | GRAFT-COPOLYMERS | - |
dc.subject.keywordPlus | ONE-POT | - |
dc.subject.keywordPlus | CHEMISTRY | - |
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.
(02841) 서울특별시 성북구 안암로 14502-3290-1114
COPYRIGHT © 2021 Korea University. All Rights Reserved.
Certain data included herein are derived from the © Web of Science of Clarivate Analytics. All rights reserved.
You may not copy or re-distribute this material in whole or in part without the prior written consent of Clarivate Analytics.