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Cost-Effective, High-Performance Porous-Organic-Polymer Conductors Functionalized with Sulfonic Acid Groups by Direct Postsynthetic Substitution

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dc.contributor.authorKang, Dong Won-
dc.contributor.authorLim, Kwang Soo-
dc.contributor.authorLee, Kyung Jin-
dc.contributor.authorLee, Jong Hyeon-
dc.contributor.authorLee, Woo Ram-
dc.contributor.authorSong, Jeong Hwa-
dc.contributor.authorYeom, Kyu Hyun-
dc.contributor.authorKim, Jin Young-
dc.contributor.authorHong, Chang Seop-
dc.date.accessioned2021-09-03T15:36:21Z-
dc.date.available2021-09-03T15:36:21Z-
dc.date.created2021-06-16-
dc.date.issued2016-12-23-
dc.identifier.issn1433-7851-
dc.identifier.urihttps://scholar.korea.ac.kr/handle/2021.sw.korea/86501-
dc.description.abstractWe demonstrate the facile microwave-assisted synthesis of a porous organic framework 1 and the sulfonated solid (1S) through postsubstitution. Remarkably, the conductivity of 1S showed an approximately 300-fold enhancement at 30 degrees C as compared to that of 1, and reached 7.72x10(-2)Scm(-1) at 80 degrees C and 90% relative humidity. The superprotonic conductivity exceeds that observed for any conductive porous organic polymer reported to date. This material, which is cost-effective and scalable for mass production, also revealed long-term performance over more than 3months without conductivity decay.-
dc.languageEnglish-
dc.language.isoen-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectPROTON CONDUCTION-
dc.subjectDIFFERENT KINDS-
dc.subjectFRAMEWORKS-
dc.subjectCATALYST-
dc.subjectESTERIFICATION-
dc.subjectCONSTRUCTION-
dc.subjectCAPTURE-
dc.subjectCARBON-
dc.subjectPORES-
dc.subjectWATER-
dc.titleCost-Effective, High-Performance Porous-Organic-Polymer Conductors Functionalized with Sulfonic Acid Groups by Direct Postsynthetic Substitution-
dc.typeArticle-
dc.contributor.affiliatedAuthorHong, Chang Seop-
dc.identifier.doi10.1002/anie.201609049-
dc.identifier.scopusid2-s2.0-85005765018-
dc.identifier.wosid000392875700030-
dc.identifier.bibliographicCitationANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.55, no.52, pp.16123 - 16126-
dc.relation.isPartOfANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.citation.titleANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.citation.volume55-
dc.citation.number52-
dc.citation.startPage16123-
dc.citation.endPage16126-
dc.type.rimsART-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusPROTON CONDUCTION-
dc.subject.keywordPlusDIFFERENT KINDS-
dc.subject.keywordPlusFRAMEWORKS-
dc.subject.keywordPlusCATALYST-
dc.subject.keywordPlusESTERIFICATION-
dc.subject.keywordPlusCONSTRUCTION-
dc.subject.keywordPlusCAPTURE-
dc.subject.keywordPlusCARBON-
dc.subject.keywordPlusPORES-
dc.subject.keywordPlusWATER-
dc.subject.keywordAuthorlong-term performance-
dc.subject.keywordAuthormicrowave chemistry-
dc.subject.keywordAuthorporous organic polymers-
dc.subject.keywordAuthorpostsynthetic substitution-
dc.subject.keywordAuthorproton-conducting materials-
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