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Magnetic resonance and magnetic susceptibility study of vanadium oxide-decylamine nanotubes

Authors
Panich, Alexander M.Felner, IsraelShames, Alexander I.Lee, Cheol Eui
Issue Date
11월-2016
Publisher
IOP PUBLISHING LTD
Keywords
vanadium oxide nanotubes; NMR; EPR; magnetic susceptibility
Citation
MATERIALS RESEARCH EXPRESS, v.3, no.11
Indexed
SCIE
SCOPUS
Journal Title
MATERIALS RESEARCH EXPRESS
Volume
3
Number
11
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/86943
DOI
10.1088/2053-1591/3/11/115019
ISSN
2053-1591
Abstract
We report on magnetic susceptibility, V-51 NMR and EPR study of multiwall vanadium oxide-decylamine nanotubes. Our measurements reveal the presence of a diamagnetic V5+ and two paramagnetic V4+ ions, respectively. NMR spectra and magnetic susceptibility data estimate the V4+ ions as similar to 31%-35% of the entire vanadium ions content. EPR evidences that the paramagnetic V4+ subsystem consists of similar to 10% of individual ions (hyperfine structured polycrystalline pattern) and similar to 90% of exchange coupled entities (Lorentzian line).
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