Thiol-epoxy "click" chemistry: Application in preparation and postpolymerization modification of polymers
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Stuparu, Mihaiela C. | - |
dc.contributor.author | Khan, Anzar | - |
dc.date.accessioned | 2021-09-03T18:55:38Z | - |
dc.date.available | 2021-09-03T18:55:38Z | - |
dc.date.created | 2021-06-16 | - |
dc.date.issued | 2016-10-01 | - |
dc.identifier.issn | 0887-624X | - |
dc.identifier.uri | https://scholar.korea.ac.kr/handle/2021.sw.korea/87219 | - |
dc.description.abstract | Base-catalyzed reaction between a thiol and an epoxide group is a simple fusion process that leads to the formation of a -hydroxythio-ether linkage. This reaction is efficient, regio-selective, and fast. In addition, it produces a reactive hydroxyl group upon completion. Therefore, it is of considerable potential in synthesis of reactive and functional soft materials. Here, we discuss the fundamental aspects of this process, the so-called thiol-epoxy click reaction, and its utility in the preparation and post-polymerization functionalization of polymers and crosslinked networks. Furthermore, its application in surface modification of solid substrates is also considered. Finally, utility of multifunctional materials created using the thiol-epoxy reaction is discussed in the biomedical arena. (c) 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 3057-3070 | - |
dc.language | English | - |
dc.language.iso | en | - |
dc.publisher | WILEY | - |
dc.subject | ONE-POT | - |
dc.subject | MULTIFUNCTIONAL POLYMERS | - |
dc.subject | HYPERBRANCHED POLYMERS | - |
dc.subject | POST-FUNCTIONALIZATION | - |
dc.subject | PHOTOBASE GENERATORS | - |
dc.subject | AMMONIUM-SALTS | - |
dc.subject | POLYMERIZATION | - |
dc.subject | EFFICIENT | - |
dc.subject | IMMOBILIZATION | - |
dc.subject | TEMPERATURE | - |
dc.title | Thiol-epoxy "click" chemistry: Application in preparation and postpolymerization modification of polymers | - |
dc.type | Article | - |
dc.contributor.affiliatedAuthor | Khan, Anzar | - |
dc.identifier.doi | 10.1002/pola.28195 | - |
dc.identifier.scopusid | 2-s2.0-84976870591 | - |
dc.identifier.wosid | 000383679000001 | - |
dc.identifier.bibliographicCitation | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.54, no.19, pp.3057 - 3070 | - |
dc.relation.isPartOf | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.citation.title | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | - |
dc.citation.volume | 54 | - |
dc.citation.number | 19 | - |
dc.citation.startPage | 3057 | - |
dc.citation.endPage | 3070 | - |
dc.type.rims | ART | - |
dc.type.docType | Article | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.subject.keywordPlus | ONE-POT | - |
dc.subject.keywordPlus | MULTIFUNCTIONAL POLYMERS | - |
dc.subject.keywordPlus | HYPERBRANCHED POLYMERS | - |
dc.subject.keywordPlus | POST-FUNCTIONALIZATION | - |
dc.subject.keywordPlus | PHOTOBASE GENERATORS | - |
dc.subject.keywordPlus | AMMONIUM-SALTS | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | IMMOBILIZATION | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.subject.keywordAuthor | click chemistry | - |
dc.subject.keywordAuthor | functionalization of polymers | - |
dc.subject.keywordAuthor | sequential reactions | - |
dc.subject.keywordAuthor | structure | - |
dc.subject.keywordAuthor | synthesis | - |
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